[N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)cyclo­hexane-1,2-diaminium-κ(4) O,O′,O′′,O′′′]tris­(nitrato-κ(2) O,O′)europium(III) methanol monosolvate

In the title mononuclear salen-type complex, [Eu(NO(3))(3)(C(22)H(26)N(2)O(4))]·CH(3)OH, the Eu(III) ion is ten-coordinated by three bidentate nitrate counter-ions and one organic salen-type ligand, which acts in a bis-bidentate chelating mode through its phenolate and meth­oxy O atoms. The protonat...

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Detalles Bibliográficos
Autores principales: Yan, Peng-Fei, Bao, Yan, Li, Guang-Ming, Li, Jing-Ya, Chen, Peng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011416/
https://www.ncbi.nlm.nih.gov/pubmed/21589317
http://dx.doi.org/10.1107/S1600536810046076
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author Yan, Peng-Fei
Bao, Yan
Li, Guang-Ming
Li, Jing-Ya
Chen, Peng
author_facet Yan, Peng-Fei
Bao, Yan
Li, Guang-Ming
Li, Jing-Ya
Chen, Peng
author_sort Yan, Peng-Fei
collection PubMed
description In the title mononuclear salen-type complex, [Eu(NO(3))(3)(C(22)H(26)N(2)O(4))]·CH(3)OH, the Eu(III) ion is ten-coordinated by three bidentate nitrate counter-ions and one organic salen-type ligand, which acts in a bis-bidentate chelating mode through its phenolate and meth­oxy O atoms. The protonated imine groups are involved in intra­molecular N—H⋯O hydrogen bonds to the phenolate O atomss, emphasizing the zwitterionic nature of the ligand. An O—H⋯O hydrogen bond links the complex and solvent mol­ecules.
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spelling pubmed-30114162010-12-30 [N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)cyclo­hexane-1,2-diaminium-κ(4) O,O′,O′′,O′′′]tris­(nitrato-κ(2) O,O′)europium(III) methanol monosolvate Yan, Peng-Fei Bao, Yan Li, Guang-Ming Li, Jing-Ya Chen, Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear salen-type complex, [Eu(NO(3))(3)(C(22)H(26)N(2)O(4))]·CH(3)OH, the Eu(III) ion is ten-coordinated by three bidentate nitrate counter-ions and one organic salen-type ligand, which acts in a bis-bidentate chelating mode through its phenolate and meth­oxy O atoms. The protonated imine groups are involved in intra­molecular N—H⋯O hydrogen bonds to the phenolate O atomss, emphasizing the zwitterionic nature of the ligand. An O—H⋯O hydrogen bond links the complex and solvent mol­ecules. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011416/ /pubmed/21589317 http://dx.doi.org/10.1107/S1600536810046076 Text en © Yan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yan, Peng-Fei
Bao, Yan
Li, Guang-Ming
Li, Jing-Ya
Chen, Peng
[N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)cyclo­hexane-1,2-diaminium-κ(4) O,O′,O′′,O′′′]tris­(nitrato-κ(2) O,O′)europium(III) methanol monosolvate
title [N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)cyclo­hexane-1,2-diaminium-κ(4) O,O′,O′′,O′′′]tris­(nitrato-κ(2) O,O′)europium(III) methanol monosolvate
title_full [N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)cyclo­hexane-1,2-diaminium-κ(4) O,O′,O′′,O′′′]tris­(nitrato-κ(2) O,O′)europium(III) methanol monosolvate
title_fullStr [N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)cyclo­hexane-1,2-diaminium-κ(4) O,O′,O′′,O′′′]tris­(nitrato-κ(2) O,O′)europium(III) methanol monosolvate
title_full_unstemmed [N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)cyclo­hexane-1,2-diaminium-κ(4) O,O′,O′′,O′′′]tris­(nitrato-κ(2) O,O′)europium(III) methanol monosolvate
title_short [N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)cyclo­hexane-1,2-diaminium-κ(4) O,O′,O′′,O′′′]tris­(nitrato-κ(2) O,O′)europium(III) methanol monosolvate
title_sort [n,n′-bis(3-meth­oxy-2-oxidobenzyl­idene)cyclo­hexane-1,2-diaminium-κ(4) o,o′,o′′,o′′′]tris­(nitrato-κ(2) o,o′)europium(iii) methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011416/
https://www.ncbi.nlm.nih.gov/pubmed/21589317
http://dx.doi.org/10.1107/S1600536810046076
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