Piperidinium N-(ferrocenylcarbon­yl)glycinate

The title compound, (C(5)H(12)N)[Fe(C(5)H(5))(C(8)H(7)NO(3))], resulting from neutralization of N-(ferrocenylcarbon­yl)glycine with piperidine, is built up from discrete ions that assemble into sheets via the combination of conventional and weak hydrogen bonds. The key repeating unit is constituted...

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Detalles Bibliográficos
Autores principales: Štěpnička, Petr, Zábranský, Martin, Císařová, Ivana
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011418/
https://www.ncbi.nlm.nih.gov/pubmed/21589213
http://dx.doi.org/10.1107/S1600536810041747
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author Štěpnička, Petr
Zábranský, Martin
Císařová, Ivana
author_facet Štěpnička, Petr
Zábranský, Martin
Císařová, Ivana
author_sort Štěpnička, Petr
collection PubMed
description The title compound, (C(5)H(12)N)[Fe(C(5)H(5))(C(8)H(7)NO(3))], resulting from neutralization of N-(ferrocenylcarbon­yl)glycine with piperidine, is built up from discrete ions that assemble into sheets via the combination of conventional and weak hydrogen bonds. The key repeating unit is constituted by two piperidium cations and two carboxylate anions that assemble into a centrosymmetric array via conventional and bifurcated N—H⋯O hydrogen bonds. The aggregates thus formed are further interlinked by N—H⋯O interactions and supportive C—H⋯O contacts into layers oriented parallel to the bc plane.
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spelling pubmed-30114182010-12-30 Piperidinium N-(ferrocenylcarbon­yl)glycinate Štěpnička, Petr Zábranský, Martin Císařová, Ivana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(5)H(12)N)[Fe(C(5)H(5))(C(8)H(7)NO(3))], resulting from neutralization of N-(ferrocenylcarbon­yl)glycine with piperidine, is built up from discrete ions that assemble into sheets via the combination of conventional and weak hydrogen bonds. The key repeating unit is constituted by two piperidium cations and two carboxylate anions that assemble into a centrosymmetric array via conventional and bifurcated N—H⋯O hydrogen bonds. The aggregates thus formed are further interlinked by N—H⋯O interactions and supportive C—H⋯O contacts into layers oriented parallel to the bc plane. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011418/ /pubmed/21589213 http://dx.doi.org/10.1107/S1600536810041747 Text en © Štěpnička et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Štěpnička, Petr
Zábranský, Martin
Císařová, Ivana
Piperidinium N-(ferrocenylcarbon­yl)glycinate
title Piperidinium N-(ferrocenylcarbon­yl)glycinate
title_full Piperidinium N-(ferrocenylcarbon­yl)glycinate
title_fullStr Piperidinium N-(ferrocenylcarbon­yl)glycinate
title_full_unstemmed Piperidinium N-(ferrocenylcarbon­yl)glycinate
title_short Piperidinium N-(ferrocenylcarbon­yl)glycinate
title_sort piperidinium n-(ferrocenylcarbon­yl)glycinate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011418/
https://www.ncbi.nlm.nih.gov/pubmed/21589213
http://dx.doi.org/10.1107/S1600536810041747
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AT zabranskymartin piperidiniumnferrocenylcarbonylglycinate
AT cisarovaivana piperidiniumnferrocenylcarbonylglycinate

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