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Aqua(4-nitrophthalato-κO (1))bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]manganese(II) hemihydrate
In the title compound, [Mn(C(8)H(3)NO(6))(C(8)H(7)N(3))(2)(H(2)O)]·0.5H(2)O, the Mn(2+) ion is octahedrally coordinated by two 2-(1H-pyrazol-3-yl)pyridine ligands, one 4-nitrophthalate ligand and one coordinated water molecule leading to an overall MnN(4)O(2) coordination environment. The two 2-(...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011419/ https://www.ncbi.nlm.nih.gov/pubmed/21589243 http://dx.doi.org/10.1107/S1600536810045952 |
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author | Ni, Lei Zhao, Ji-Li Wei, Hong |
author_facet | Ni, Lei Zhao, Ji-Li Wei, Hong |
author_sort | Ni, Lei |
collection | PubMed |
description | In the title compound, [Mn(C(8)H(3)NO(6))(C(8)H(7)N(3))(2)(H(2)O)]·0.5H(2)O, the Mn(2+) ion is octahedrally coordinated by two 2-(1H-pyrazol-3-yl)pyridine ligands, one 4-nitrophthalate ligand and one coordinated water molecule leading to an overall MnN(4)O(2) coordination environment. The two 2-(1H-pyrazol-3-yl)pyridine ligands, which deviate from planarity by 0.0187 (2) and 0.0601 (2) Å, make a dihedral angle of 81.90 (6)°. An intramolecular N—H⋯O hydrogen bond occurs. Intermolecular π–π stacking interactions with a face-to-face separation of 3.61 (1) Å between the 2-(1H-pyrazol-3-yl)pyridine ligands is observed. Additionally, O—H⋯O hydrogen bonding involving the uncoordinated water (which is situated on an inversion center), coordinated water molecules and 2-(1H-pyrazol-3-yl)pyridine ligands leads to a three-dimensional network in the crystal structure. |
format | Text |
id | pubmed-3011419 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30114192010-12-30 Aqua(4-nitrophthalato-κO (1))bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]manganese(II) hemihydrate Ni, Lei Zhao, Ji-Li Wei, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(8)H(3)NO(6))(C(8)H(7)N(3))(2)(H(2)O)]·0.5H(2)O, the Mn(2+) ion is octahedrally coordinated by two 2-(1H-pyrazol-3-yl)pyridine ligands, one 4-nitrophthalate ligand and one coordinated water molecule leading to an overall MnN(4)O(2) coordination environment. The two 2-(1H-pyrazol-3-yl)pyridine ligands, which deviate from planarity by 0.0187 (2) and 0.0601 (2) Å, make a dihedral angle of 81.90 (6)°. An intramolecular N—H⋯O hydrogen bond occurs. Intermolecular π–π stacking interactions with a face-to-face separation of 3.61 (1) Å between the 2-(1H-pyrazol-3-yl)pyridine ligands is observed. Additionally, O—H⋯O hydrogen bonding involving the uncoordinated water (which is situated on an inversion center), coordinated water molecules and 2-(1H-pyrazol-3-yl)pyridine ligands leads to a three-dimensional network in the crystal structure. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011419/ /pubmed/21589243 http://dx.doi.org/10.1107/S1600536810045952 Text en © Ni et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ni, Lei Zhao, Ji-Li Wei, Hong Aqua(4-nitrophthalato-κO (1))bis[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]manganese(II) hemihydrate |
title | Aqua(4-nitrophthalato-κO
(1))bis[2-(1H-pyrazol-3-yl-κN
(2))pyridine-κN]manganese(II) hemihydrate |
title_full | Aqua(4-nitrophthalato-κO
(1))bis[2-(1H-pyrazol-3-yl-κN
(2))pyridine-κN]manganese(II) hemihydrate |
title_fullStr | Aqua(4-nitrophthalato-κO
(1))bis[2-(1H-pyrazol-3-yl-κN
(2))pyridine-κN]manganese(II) hemihydrate |
title_full_unstemmed | Aqua(4-nitrophthalato-κO
(1))bis[2-(1H-pyrazol-3-yl-κN
(2))pyridine-κN]manganese(II) hemihydrate |
title_short | Aqua(4-nitrophthalato-κO
(1))bis[2-(1H-pyrazol-3-yl-κN
(2))pyridine-κN]manganese(II) hemihydrate |
title_sort | aqua(4-nitrophthalato-κo
(1))bis[2-(1h-pyrazol-3-yl-κn
(2))pyridine-κn]manganese(ii) hemihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011419/ https://www.ncbi.nlm.nih.gov/pubmed/21589243 http://dx.doi.org/10.1107/S1600536810045952 |
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