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Aqua­(4-nitro­phthalato-κO (1))bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]­mangan­ese(II) hemihydrate

In the title compound, [Mn(C(8)H(3)NO(6))(C(8)H(7)N(3))(2)(H(2)O)]·0.5H(2)O, the Mn(2+) ion is octa­hedrally coordinated by two 2-(1H-pyrazol-3-yl)pyridine ligands, one 4-nitro­phthalate ligand and one coordinated water mol­ecule leading to an overall MnN(4)O(2) coordination environment. The two 2-(...

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Detalles Bibliográficos
Autores principales: Ni, Lei, Zhao, Ji-Li, Wei, Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011419/
https://www.ncbi.nlm.nih.gov/pubmed/21589243
http://dx.doi.org/10.1107/S1600536810045952
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author Ni, Lei
Zhao, Ji-Li
Wei, Hong
author_facet Ni, Lei
Zhao, Ji-Li
Wei, Hong
author_sort Ni, Lei
collection PubMed
description In the title compound, [Mn(C(8)H(3)NO(6))(C(8)H(7)N(3))(2)(H(2)O)]·0.5H(2)O, the Mn(2+) ion is octa­hedrally coordinated by two 2-(1H-pyrazol-3-yl)pyridine ligands, one 4-nitro­phthalate ligand and one coordinated water mol­ecule leading to an overall MnN(4)O(2) coordination environment. The two 2-(1H-pyrazol-3-yl)pyridine ligands, which deviate from planarity by 0.0187 (2) and 0.0601 (2) Å, make a dihedral angle of 81.90 (6)°. An intra­molecular N—H⋯O hydrogen bond occurs. Inter­molecular π–π stacking inter­actions with a face-to-face separation of 3.61 (1) Å between the 2-(1H-pyrazol-3-yl)pyridine ligands is observed. Additionally, O—H⋯O hydrogen bonding involving the uncoordinated water (which is situated on an inversion center), coordinated water mol­ecules and 2-(1H-pyrazol-3-yl)pyridine ligands leads to a three-dimensional network in the crystal structure.
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spelling pubmed-30114192010-12-30 Aqua­(4-nitro­phthalato-κO (1))bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]­mangan­ese(II) hemihydrate Ni, Lei Zhao, Ji-Li Wei, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(8)H(3)NO(6))(C(8)H(7)N(3))(2)(H(2)O)]·0.5H(2)O, the Mn(2+) ion is octa­hedrally coordinated by two 2-(1H-pyrazol-3-yl)pyridine ligands, one 4-nitro­phthalate ligand and one coordinated water mol­ecule leading to an overall MnN(4)O(2) coordination environment. The two 2-(1H-pyrazol-3-yl)pyridine ligands, which deviate from planarity by 0.0187 (2) and 0.0601 (2) Å, make a dihedral angle of 81.90 (6)°. An intra­molecular N—H⋯O hydrogen bond occurs. Inter­molecular π–π stacking inter­actions with a face-to-face separation of 3.61 (1) Å between the 2-(1H-pyrazol-3-yl)pyridine ligands is observed. Additionally, O—H⋯O hydrogen bonding involving the uncoordinated water (which is situated on an inversion center), coordinated water mol­ecules and 2-(1H-pyrazol-3-yl)pyridine ligands leads to a three-dimensional network in the crystal structure. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011419/ /pubmed/21589243 http://dx.doi.org/10.1107/S1600536810045952 Text en © Ni et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ni, Lei
Zhao, Ji-Li
Wei, Hong
Aqua­(4-nitro­phthalato-κO (1))bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]­mangan­ese(II) hemihydrate
title Aqua­(4-nitro­phthalato-κO (1))bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]­mangan­ese(II) hemihydrate
title_full Aqua­(4-nitro­phthalato-κO (1))bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]­mangan­ese(II) hemihydrate
title_fullStr Aqua­(4-nitro­phthalato-κO (1))bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]­mangan­ese(II) hemihydrate
title_full_unstemmed Aqua­(4-nitro­phthalato-κO (1))bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]­mangan­ese(II) hemihydrate
title_short Aqua­(4-nitro­phthalato-κO (1))bis­[2-(1H-pyrazol-3-yl-κN (2))pyridine-κN]­mangan­ese(II) hemihydrate
title_sort aqua­(4-nitro­phthalato-κo (1))bis­[2-(1h-pyrazol-3-yl-κn (2))pyridine-κn]­mangan­ese(ii) hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011419/
https://www.ncbi.nlm.nih.gov/pubmed/21589243
http://dx.doi.org/10.1107/S1600536810045952
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