4,4′-Bipyridine–2-(carb­oxy­methyl­sulfan­yl)pyridine-3-carb­oxy­lic acid (1/1)

In the title co-crystal, C(10)H(8)N(2)·C(8)H(7)NO(4)S, the formate group is coplanar with the pyridyl ring of the acid [dihedral angle = 6.2 (7)°], while the carb­oxy­methyl­sulfanyl group makes a C—S—C—C torsion angle of 70.2 (1)° with the pyridine ring. The dihedral angle between the pyridyl rings...

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Detalles Bibliográficos
Autores principales: Jiang, Xian-Rong, Wang, Xiao-Juan, Feng, Yun-Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011421/
https://www.ncbi.nlm.nih.gov/pubmed/21589586
http://dx.doi.org/10.1107/S1600536810048385
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author Jiang, Xian-Rong
Wang, Xiao-Juan
Feng, Yun-Long
author_facet Jiang, Xian-Rong
Wang, Xiao-Juan
Feng, Yun-Long
author_sort Jiang, Xian-Rong
collection PubMed
description In the title co-crystal, C(10)H(8)N(2)·C(8)H(7)NO(4)S, the formate group is coplanar with the pyridyl ring of the acid [dihedral angle = 6.2 (7)°], while the carb­oxy­methyl­sulfanyl group makes a C—S—C—C torsion angle of 70.2 (1)° with the pyridine ring. The dihedral angle between the pyridyl rings of the 4,4′-bipyridine mol­ecule is 27.4 (1)°. The acid and the 4,4′-bipyridine mol­ecules are involved in hydrogen bonding via carb­oxy­lic O and pyridyl N atoms. The structure is further consolidated by inter­molecular C—H⋯O hydrogen bonds, generating a three-dimensional network.
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spelling pubmed-30114212010-12-30 4,4′-Bipyridine–2-(carb­oxy­methyl­sulfan­yl)pyridine-3-carb­oxy­lic acid (1/1) Jiang, Xian-Rong Wang, Xiao-Juan Feng, Yun-Long Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title co-crystal, C(10)H(8)N(2)·C(8)H(7)NO(4)S, the formate group is coplanar with the pyridyl ring of the acid [dihedral angle = 6.2 (7)°], while the carb­oxy­methyl­sulfanyl group makes a C—S—C—C torsion angle of 70.2 (1)° with the pyridine ring. The dihedral angle between the pyridyl rings of the 4,4′-bipyridine mol­ecule is 27.4 (1)°. The acid and the 4,4′-bipyridine mol­ecules are involved in hydrogen bonding via carb­oxy­lic O and pyridyl N atoms. The structure is further consolidated by inter­molecular C—H⋯O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011421/ /pubmed/21589586 http://dx.doi.org/10.1107/S1600536810048385 Text en © Jiang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jiang, Xian-Rong
Wang, Xiao-Juan
Feng, Yun-Long
4,4′-Bipyridine–2-(carb­oxy­methyl­sulfan­yl)pyridine-3-carb­oxy­lic acid (1/1)
title 4,4′-Bipyridine–2-(carb­oxy­methyl­sulfan­yl)pyridine-3-carb­oxy­lic acid (1/1)
title_full 4,4′-Bipyridine–2-(carb­oxy­methyl­sulfan­yl)pyridine-3-carb­oxy­lic acid (1/1)
title_fullStr 4,4′-Bipyridine–2-(carb­oxy­methyl­sulfan­yl)pyridine-3-carb­oxy­lic acid (1/1)
title_full_unstemmed 4,4′-Bipyridine–2-(carb­oxy­methyl­sulfan­yl)pyridine-3-carb­oxy­lic acid (1/1)
title_short 4,4′-Bipyridine–2-(carb­oxy­methyl­sulfan­yl)pyridine-3-carb­oxy­lic acid (1/1)
title_sort 4,4′-bipyridine–2-(carb­oxy­methyl­sulfan­yl)pyridine-3-carb­oxy­lic acid (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011421/
https://www.ncbi.nlm.nih.gov/pubmed/21589586
http://dx.doi.org/10.1107/S1600536810048385
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AT wangxiaojuan 44bipyridine2carboxymethylsulfanylpyridine3carboxylicacid11
AT fengyunlong 44bipyridine2carboxymethylsulfanylpyridine3carboxylicacid11

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