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3,3′-Dimethyl-1,1′-[(1,3-dihydroxypropane-2,2-diyl)dimethylidene]diimidazolium bis(hexafluorophosphate)
The title compound, C(13)H(22)N(4)O(2) (2+)·2PF(6) (−), was prepared by the anion exchange of the dibromide ionic liquid with potassium hexafluorophosphate. The two imidazole rings are each planar (r.m.s. deviations = 0.0016 and 0.0060 Å) and make a dihedral angle of 45.3 (18)°. Intramolecular O—...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011425/ https://www.ncbi.nlm.nih.gov/pubmed/21589562 http://dx.doi.org/10.1107/S1600536810047677 |
| _version_ | 1782194937764249600 |
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| author | Yuan, Ai-Lin Wang, Chang-Sheng Zhuang, Ling-Hua Wang, Guo-Wei |
| author_facet | Yuan, Ai-Lin Wang, Chang-Sheng Zhuang, Ling-Hua Wang, Guo-Wei |
| author_sort | Yuan, Ai-Lin |
| collection | PubMed |
| description | The title compound, C(13)H(22)N(4)O(2) (2+)·2PF(6) (−), was prepared by the anion exchange of the dibromide ionic liquid with potassium hexafluorophosphate. The two imidazole rings are each planar (r.m.s. deviations = 0.0016 and 0.0060 Å) and make a dihedral angle of 45.3 (18)°. Intramolecular O—H⋯F hydrogen bonds occur. Intermolecular C—H⋯F, O—H⋯O and C—H⋯O hydrogen bonds stabilize the crystal structure. |
| format | Text |
| id | pubmed-3011425 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30114252010-12-30 3,3′-Dimethyl-1,1′-[(1,3-dihydroxypropane-2,2-diyl)dimethylidene]diimidazolium bis(hexafluorophosphate) Yuan, Ai-Lin Wang, Chang-Sheng Zhuang, Ling-Hua Wang, Guo-Wei Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(22)N(4)O(2) (2+)·2PF(6) (−), was prepared by the anion exchange of the dibromide ionic liquid with potassium hexafluorophosphate. The two imidazole rings are each planar (r.m.s. deviations = 0.0016 and 0.0060 Å) and make a dihedral angle of 45.3 (18)°. Intramolecular O—H⋯F hydrogen bonds occur. Intermolecular C—H⋯F, O—H⋯O and C—H⋯O hydrogen bonds stabilize the crystal structure. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011425/ /pubmed/21589562 http://dx.doi.org/10.1107/S1600536810047677 Text en © Yuan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Yuan, Ai-Lin Wang, Chang-Sheng Zhuang, Ling-Hua Wang, Guo-Wei 3,3′-Dimethyl-1,1′-[(1,3-dihydroxypropane-2,2-diyl)dimethylidene]diimidazolium bis(hexafluorophosphate) |
| title | 3,3′-Dimethyl-1,1′-[(1,3-dihydroxypropane-2,2-diyl)dimethylidene]diimidazolium bis(hexafluorophosphate) |
| title_full | 3,3′-Dimethyl-1,1′-[(1,3-dihydroxypropane-2,2-diyl)dimethylidene]diimidazolium bis(hexafluorophosphate) |
| title_fullStr | 3,3′-Dimethyl-1,1′-[(1,3-dihydroxypropane-2,2-diyl)dimethylidene]diimidazolium bis(hexafluorophosphate) |
| title_full_unstemmed | 3,3′-Dimethyl-1,1′-[(1,3-dihydroxypropane-2,2-diyl)dimethylidene]diimidazolium bis(hexafluorophosphate) |
| title_short | 3,3′-Dimethyl-1,1′-[(1,3-dihydroxypropane-2,2-diyl)dimethylidene]diimidazolium bis(hexafluorophosphate) |
| title_sort | 3,3′-dimethyl-1,1′-[(1,3-dihydroxypropane-2,2-diyl)dimethylidene]diimidazolium bis(hexafluorophosphate) |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011425/ https://www.ncbi.nlm.nih.gov/pubmed/21589562 http://dx.doi.org/10.1107/S1600536810047677 |
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