tert-Butyl 6-amino-3,4-dihydro-2H-1,4-benzoxazine-4-carboxyl­ate

The title mol­ecule, C(13)H(18)N(2)O(3), contains a benzene ring fused to an oxazine ring and one tert-but­oxy­carbonyl group bound to the N atom of the oxazine ring. A weak intra­molecular C—H⋯O inter­action occurs. In the crystal, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds stack the mol­ecules...

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Detalles Bibliográficos
Autores principales: Gu, Xiao-Bo, Jiang, Meng-Jun, Cai, Gang-Ming, Zhou, Yao-Yuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011429/
https://www.ncbi.nlm.nih.gov/pubmed/21589552
http://dx.doi.org/10.1107/S160053681004777X
Descripción
Sumario:The title mol­ecule, C(13)H(18)N(2)O(3), contains a benzene ring fused to an oxazine ring and one tert-but­oxy­carbonyl group bound to the N atom of the oxazine ring. A weak intra­molecular C—H⋯O inter­action occurs. In the crystal, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds stack the mol­ecules down the b axis. Weak C—H⋯N contacts connect the stacks, generating a three-dimensional network.

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