tert-Butyl 6-amino-3,4-dihydro-2H-1,4-benzoxazine-4-carboxyl­ate

The title mol­ecule, C(13)H(18)N(2)O(3), contains a benzene ring fused to an oxazine ring and one tert-but­oxy­carbonyl group bound to the N atom of the oxazine ring. A weak intra­molecular C—H⋯O inter­action occurs. In the crystal, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds stack the mol­ecules...

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Detalles Bibliográficos
Autores principales: Gu, Xiao-Bo, Jiang, Meng-Jun, Cai, Gang-Ming, Zhou, Yao-Yuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011429/
https://www.ncbi.nlm.nih.gov/pubmed/21589552
http://dx.doi.org/10.1107/S160053681004777X
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author Gu, Xiao-Bo
Jiang, Meng-Jun
Cai, Gang-Ming
Zhou, Yao-Yuan
author_facet Gu, Xiao-Bo
Jiang, Meng-Jun
Cai, Gang-Ming
Zhou, Yao-Yuan
author_sort Gu, Xiao-Bo
collection PubMed
description The title mol­ecule, C(13)H(18)N(2)O(3), contains a benzene ring fused to an oxazine ring and one tert-but­oxy­carbonyl group bound to the N atom of the oxazine ring. A weak intra­molecular C—H⋯O inter­action occurs. In the crystal, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds stack the mol­ecules down the b axis. Weak C—H⋯N contacts connect the stacks, generating a three-dimensional network.
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spelling pubmed-30114292010-12-30 tert-Butyl 6-amino-3,4-dihydro-2H-1,4-benzoxazine-4-carboxyl­ate Gu, Xiao-Bo Jiang, Meng-Jun Cai, Gang-Ming Zhou, Yao-Yuan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(13)H(18)N(2)O(3), contains a benzene ring fused to an oxazine ring and one tert-but­oxy­carbonyl group bound to the N atom of the oxazine ring. A weak intra­molecular C—H⋯O inter­action occurs. In the crystal, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds stack the mol­ecules down the b axis. Weak C—H⋯N contacts connect the stacks, generating a three-dimensional network. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011429/ /pubmed/21589552 http://dx.doi.org/10.1107/S160053681004777X Text en © Gu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gu, Xiao-Bo
Jiang, Meng-Jun
Cai, Gang-Ming
Zhou, Yao-Yuan
tert-Butyl 6-amino-3,4-dihydro-2H-1,4-benzoxazine-4-carboxyl­ate
title tert-Butyl 6-amino-3,4-dihydro-2H-1,4-benzoxazine-4-carboxyl­ate
title_full tert-Butyl 6-amino-3,4-dihydro-2H-1,4-benzoxazine-4-carboxyl­ate
title_fullStr tert-Butyl 6-amino-3,4-dihydro-2H-1,4-benzoxazine-4-carboxyl­ate
title_full_unstemmed tert-Butyl 6-amino-3,4-dihydro-2H-1,4-benzoxazine-4-carboxyl­ate
title_short tert-Butyl 6-amino-3,4-dihydro-2H-1,4-benzoxazine-4-carboxyl­ate
title_sort tert-butyl 6-amino-3,4-dihydro-2h-1,4-benzoxazine-4-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011429/
https://www.ncbi.nlm.nih.gov/pubmed/21589552
http://dx.doi.org/10.1107/S160053681004777X
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AT jiangmengjun tertbutyl6amino34dihydro2h14benzoxazine4carboxylate
AT caigangming tertbutyl6amino34dihydro2h14benzoxazine4carboxylate
AT zhouyaoyuan tertbutyl6amino34dihydro2h14benzoxazine4carboxylate

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