Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl-κN (3))nicotinato-κN]manganese(II)

In the title compound, [Mn(C(13)H(14)N(3)O(3))(2)(H(2)O)(2)], the Mn(II) ion is coordinated by four N atoms from two (±)-2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinate ligands and two water mol­ecules in a distorted octa­hedral environment. Inter­molecular O—H⋯O hydrogen bonds...

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Detalles Bibliográficos
Autores principales: Gao, Peng, Liu, Ji-Zhong, Zhang, Zhong, Huang, Zhong-Jing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011436/
https://www.ncbi.nlm.nih.gov/pubmed/21589328
http://dx.doi.org/10.1107/S1600536810048506
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author Gao, Peng
Liu, Ji-Zhong
Zhang, Zhong
Huang, Zhong-Jing
author_facet Gao, Peng
Liu, Ji-Zhong
Zhang, Zhong
Huang, Zhong-Jing
author_sort Gao, Peng
collection PubMed
description In the title compound, [Mn(C(13)H(14)N(3)O(3))(2)(H(2)O)(2)], the Mn(II) ion is coordinated by four N atoms from two (±)-2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinate ligands and two water mol­ecules in a distorted octa­hedral environment. Inter­molecular O—H⋯O hydrogen bonds lead to a chain along [010]. Intra­molecular N—H⋯O and O—H⋯O hydrogen bonds are observed.
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spelling pubmed-30114362010-12-30 Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl-κN (3))nicotinato-κN]manganese(II) Gao, Peng Liu, Ji-Zhong Zhang, Zhong Huang, Zhong-Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(13)H(14)N(3)O(3))(2)(H(2)O)(2)], the Mn(II) ion is coordinated by four N atoms from two (±)-2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinate ligands and two water mol­ecules in a distorted octa­hedral environment. Inter­molecular O—H⋯O hydrogen bonds lead to a chain along [010]. Intra­molecular N—H⋯O and O—H⋯O hydrogen bonds are observed. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011436/ /pubmed/21589328 http://dx.doi.org/10.1107/S1600536810048506 Text en © Gao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Peng
Liu, Ji-Zhong
Zhang, Zhong
Huang, Zhong-Jing
Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl-κN (3))nicotinato-κN]manganese(II)
title Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl-κN (3))nicotinato-κN]manganese(II)
title_full Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl-κN (3))nicotinato-κN]manganese(II)
title_fullStr Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl-κN (3))nicotinato-κN]manganese(II)
title_full_unstemmed Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl-κN (3))nicotinato-κN]manganese(II)
title_short Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl-κN (3))nicotinato-κN]manganese(II)
title_sort diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1h-imidazol-2-yl-κn (3))nicotinato-κn]manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011436/
https://www.ncbi.nlm.nih.gov/pubmed/21589328
http://dx.doi.org/10.1107/S1600536810048506
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AT zhangzhong diaquabis25isopropyl5methyl4oxo45dihydro1himidazol2ylkn3nicotinatoknmanganeseii
AT huangzhongjing diaquabis25isopropyl5methyl4oxo45dihydro1himidazol2ylkn3nicotinatoknmanganeseii

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