Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinato]cobalt(II)

In the title complex, [Co(C(13)H(14)N(3)O(3))(2)(H(2)O)(2)], the Co(II) atom has a distorted octa­hedral coordination, formed by four N atoms from two (±)-2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinate ligands and two O atoms from two water mol­ecules. Intra­molecular N—H⋯O an...

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Detalles Bibliográficos
Autores principales: Zhang, Zhong, Liu, Ji-Zhong, Gao, Peng, Huang, Zhong-Jing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011445/
https://www.ncbi.nlm.nih.gov/pubmed/21589239
http://dx.doi.org/10.1107/S1600536810044715
Descripción
Sumario:In the title complex, [Co(C(13)H(14)N(3)O(3))(2)(H(2)O)(2)], the Co(II) atom has a distorted octa­hedral coordination, formed by four N atoms from two (±)-2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinate ligands and two O atoms from two water mol­ecules. Intra­molecular N—H⋯O and O—H⋯O hydrogen bonds are present. In the crystal, inter­molecular O—H⋯O hydrogen bonds link the complex mol­ecules into a chain along [010].

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