Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinato]cobalt(II)

In the title complex, [Co(C(13)H(14)N(3)O(3))(2)(H(2)O)(2)], the Co(II) atom has a distorted octa­hedral coordination, formed by four N atoms from two (±)-2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinate ligands and two O atoms from two water mol­ecules. Intra­molecular N—H⋯O an...

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Detalles Bibliográficos
Autores principales: Zhang, Zhong, Liu, Ji-Zhong, Gao, Peng, Huang, Zhong-Jing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011445/
https://www.ncbi.nlm.nih.gov/pubmed/21589239
http://dx.doi.org/10.1107/S1600536810044715
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author Zhang, Zhong
Liu, Ji-Zhong
Gao, Peng
Huang, Zhong-Jing
author_facet Zhang, Zhong
Liu, Ji-Zhong
Gao, Peng
Huang, Zhong-Jing
author_sort Zhang, Zhong
collection PubMed
description In the title complex, [Co(C(13)H(14)N(3)O(3))(2)(H(2)O)(2)], the Co(II) atom has a distorted octa­hedral coordination, formed by four N atoms from two (±)-2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinate ligands and two O atoms from two water mol­ecules. Intra­molecular N—H⋯O and O—H⋯O hydrogen bonds are present. In the crystal, inter­molecular O—H⋯O hydrogen bonds link the complex mol­ecules into a chain along [010].
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spelling pubmed-30114452010-12-30 Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinato]cobalt(II) Zhang, Zhong Liu, Ji-Zhong Gao, Peng Huang, Zhong-Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(13)H(14)N(3)O(3))(2)(H(2)O)(2)], the Co(II) atom has a distorted octa­hedral coordination, formed by four N atoms from two (±)-2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinate ligands and two O atoms from two water mol­ecules. Intra­molecular N—H⋯O and O—H⋯O hydrogen bonds are present. In the crystal, inter­molecular O—H⋯O hydrogen bonds link the complex mol­ecules into a chain along [010]. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011445/ /pubmed/21589239 http://dx.doi.org/10.1107/S1600536810044715 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Zhong
Liu, Ji-Zhong
Gao, Peng
Huang, Zhong-Jing
Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinato]cobalt(II)
title Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinato]cobalt(II)
title_full Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinato]cobalt(II)
title_fullStr Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinato]cobalt(II)
title_full_unstemmed Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinato]cobalt(II)
title_short Diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinato]cobalt(II)
title_sort diaqua­bis­[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1h-imidazol-2-yl)nicotinato]cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011445/
https://www.ncbi.nlm.nih.gov/pubmed/21589239
http://dx.doi.org/10.1107/S1600536810044715
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