Bromidotricarbon­yl[4-chloro-N-(2-pyridyl­methyl­idene)aniline-κ(2) N,N′]rhenium(I)

In the title compound, [ReBr(C(12)H(9)ClN(2))(CO)(3)], the Re(I) atom has a distorted octa­hedral configuration with the three carbonyl ligands showing a facial arrangement. The main distortion of the octa­hedron is due to a small bite angle of the chelating bidentate diimine ligand [N—Re—N = 75.3 (...

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Detalles Bibliográficos
Autores principales: Khalaj, Mehdi, Dehghanpour, Saeed, Aleeshah, Roghaieh, Mahmoudi, Ali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011448/
https://www.ncbi.nlm.nih.gov/pubmed/21589315
http://dx.doi.org/10.1107/S1600536810044211
Descripción
Sumario:In the title compound, [ReBr(C(12)H(9)ClN(2))(CO)(3)], the Re(I) atom has a distorted octa­hedral configuration with the three carbonyl ligands showing a facial arrangement. The main distortion of the octa­hedron is due to a small bite angle of the chelating bidentate diimine ligand [N—Re—N = 75.3 (3)°].

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