Bromidotricarbon­yl[4-chloro-N-(2-pyridyl­methyl­idene)aniline-κ(2) N,N′]rhenium(I)

In the title compound, [ReBr(C(12)H(9)ClN(2))(CO)(3)], the Re(I) atom has a distorted octa­hedral configuration with the three carbonyl ligands showing a facial arrangement. The main distortion of the octa­hedron is due to a small bite angle of the chelating bidentate diimine ligand [N—Re—N = 75.3 (...

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Autores principales: Khalaj, Mehdi, Dehghanpour, Saeed, Aleeshah, Roghaieh, Mahmoudi, Ali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011448/
https://www.ncbi.nlm.nih.gov/pubmed/21589315
http://dx.doi.org/10.1107/S1600536810044211
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author Khalaj, Mehdi
Dehghanpour, Saeed
Aleeshah, Roghaieh
Mahmoudi, Ali
author_facet Khalaj, Mehdi
Dehghanpour, Saeed
Aleeshah, Roghaieh
Mahmoudi, Ali
author_sort Khalaj, Mehdi
collection PubMed
description In the title compound, [ReBr(C(12)H(9)ClN(2))(CO)(3)], the Re(I) atom has a distorted octa­hedral configuration with the three carbonyl ligands showing a facial arrangement. The main distortion of the octa­hedron is due to a small bite angle of the chelating bidentate diimine ligand [N—Re—N = 75.3 (3)°].
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spelling pubmed-30114482010-12-30 Bromidotricarbon­yl[4-chloro-N-(2-pyridyl­methyl­idene)aniline-κ(2) N,N′]rhenium(I) Khalaj, Mehdi Dehghanpour, Saeed Aleeshah, Roghaieh Mahmoudi, Ali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ReBr(C(12)H(9)ClN(2))(CO)(3)], the Re(I) atom has a distorted octa­hedral configuration with the three carbonyl ligands showing a facial arrangement. The main distortion of the octa­hedron is due to a small bite angle of the chelating bidentate diimine ligand [N—Re—N = 75.3 (3)°]. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011448/ /pubmed/21589315 http://dx.doi.org/10.1107/S1600536810044211 Text en © Khalaj et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Khalaj, Mehdi
Dehghanpour, Saeed
Aleeshah, Roghaieh
Mahmoudi, Ali
Bromidotricarbon­yl[4-chloro-N-(2-pyridyl­methyl­idene)aniline-κ(2) N,N′]rhenium(I)
title Bromidotricarbon­yl[4-chloro-N-(2-pyridyl­methyl­idene)aniline-κ(2) N,N′]rhenium(I)
title_full Bromidotricarbon­yl[4-chloro-N-(2-pyridyl­methyl­idene)aniline-κ(2) N,N′]rhenium(I)
title_fullStr Bromidotricarbon­yl[4-chloro-N-(2-pyridyl­methyl­idene)aniline-κ(2) N,N′]rhenium(I)
title_full_unstemmed Bromidotricarbon­yl[4-chloro-N-(2-pyridyl­methyl­idene)aniline-κ(2) N,N′]rhenium(I)
title_short Bromidotricarbon­yl[4-chloro-N-(2-pyridyl­methyl­idene)aniline-κ(2) N,N′]rhenium(I)
title_sort bromidotricarbon­yl[4-chloro-n-(2-pyridyl­methyl­idene)aniline-κ(2) n,n′]rhenium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011448/
https://www.ncbi.nlm.nih.gov/pubmed/21589315
http://dx.doi.org/10.1107/S1600536810044211
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AT aleeshahroghaieh bromidotricarbonyl4chloron2pyridylmethylideneanilinek2nnrheniumi
AT mahmoudiali bromidotricarbonyl4chloron2pyridylmethylideneanilinek2nnrheniumi

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