Zn(1.86)Cd(0.14)(OH)VO(4)

The title compound, dizinc cadmium hydroxide tetraoxido­vanadate, Zn(1.86)Cd(0.14)(OH)VO(4), was prepared under low-temperature hydro­thermal conditions. It is isostructural with Zn(2)(OH)VO(4) and Cu(2)(OH)VO(4). In the crystal structure, chains of edge-sharing [ZnO(6)] octahedra are inter­connecte...

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Detalles Bibliográficos
Autores principales: Đorđević, Tamara, Stojanović, Jovica, Karanović, Ljiljana
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011449/
https://www.ncbi.nlm.nih.gov/pubmed/21589202
http://dx.doi.org/10.1107/S1600536810044806
Descripción
Sumario:The title compound, dizinc cadmium hydroxide tetraoxido­vanadate, Zn(1.86)Cd(0.14)(OH)VO(4), was prepared under low-temperature hydro­thermal conditions. It is isostructural with Zn(2)(OH)VO(4) and Cu(2)(OH)VO(4). In the crystal structure, chains of edge-sharing [ZnO(6)] octahedra are inter­connected by VO(4) tetra­hedra (site symmetries of both V atoms and their coordination polyhedra are .m.) to form a three-dimensional [Zn(OH)VO(4)](2−) framework with channels occupied by Zn and Zn/Cd cations adopting trigonal–bipyramidal and distorted octa­hedral coordinations, respectively. Zn(1.86)Cd(0.14)(OH)VO(4) is topologically related to adamite-type phases, and descloizite- and tsumcorite-type structures.

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