Zn(1.86)Cd(0.14)(OH)VO(4)

The title compound, dizinc cadmium hydroxide tetraoxido­vanadate, Zn(1.86)Cd(0.14)(OH)VO(4), was prepared under low-temperature hydro­thermal conditions. It is isostructural with Zn(2)(OH)VO(4) and Cu(2)(OH)VO(4). In the crystal structure, chains of edge-sharing [ZnO(6)] octahedra are inter­connecte...

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Detalles Bibliográficos
Autores principales: Đorđević, Tamara, Stojanović, Jovica, Karanović, Ljiljana
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011449/
https://www.ncbi.nlm.nih.gov/pubmed/21589202
http://dx.doi.org/10.1107/S1600536810044806
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author Đorđević, Tamara
Stojanović, Jovica
Karanović, Ljiljana
author_facet Đorđević, Tamara
Stojanović, Jovica
Karanović, Ljiljana
author_sort Đorđević, Tamara
collection PubMed
description The title compound, dizinc cadmium hydroxide tetraoxido­vanadate, Zn(1.86)Cd(0.14)(OH)VO(4), was prepared under low-temperature hydro­thermal conditions. It is isostructural with Zn(2)(OH)VO(4) and Cu(2)(OH)VO(4). In the crystal structure, chains of edge-sharing [ZnO(6)] octahedra are inter­connected by VO(4) tetra­hedra (site symmetries of both V atoms and their coordination polyhedra are .m.) to form a three-dimensional [Zn(OH)VO(4)](2−) framework with channels occupied by Zn and Zn/Cd cations adopting trigonal–bipyramidal and distorted octa­hedral coordinations, respectively. Zn(1.86)Cd(0.14)(OH)VO(4) is topologically related to adamite-type phases, and descloizite- and tsumcorite-type structures.
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spelling pubmed-30114492010-12-30 Zn(1.86)Cd(0.14)(OH)VO(4) Đorđević, Tamara Stojanović, Jovica Karanović, Ljiljana Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, dizinc cadmium hydroxide tetraoxido­vanadate, Zn(1.86)Cd(0.14)(OH)VO(4), was prepared under low-temperature hydro­thermal conditions. It is isostructural with Zn(2)(OH)VO(4) and Cu(2)(OH)VO(4). In the crystal structure, chains of edge-sharing [ZnO(6)] octahedra are inter­connected by VO(4) tetra­hedra (site symmetries of both V atoms and their coordination polyhedra are .m.) to form a three-dimensional [Zn(OH)VO(4)](2−) framework with channels occupied by Zn and Zn/Cd cations adopting trigonal–bipyramidal and distorted octa­hedral coordinations, respectively. Zn(1.86)Cd(0.14)(OH)VO(4) is topologically related to adamite-type phases, and descloizite- and tsumcorite-type structures. International Union of Crystallography 2010-11-10 /pmc/articles/PMC3011449/ /pubmed/21589202 http://dx.doi.org/10.1107/S1600536810044806 Text en © Đorđević et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Đorđević, Tamara
Stojanović, Jovica
Karanović, Ljiljana
Zn(1.86)Cd(0.14)(OH)VO(4)
title Zn(1.86)Cd(0.14)(OH)VO(4)
title_full Zn(1.86)Cd(0.14)(OH)VO(4)
title_fullStr Zn(1.86)Cd(0.14)(OH)VO(4)
title_full_unstemmed Zn(1.86)Cd(0.14)(OH)VO(4)
title_short Zn(1.86)Cd(0.14)(OH)VO(4)
title_sort zn(1.86)cd(0.14)(oh)vo(4)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011449/
https://www.ncbi.nlm.nih.gov/pubmed/21589202
http://dx.doi.org/10.1107/S1600536810044806
work_keys_str_mv AT đorđevictamara zn186cd014ohvo4
AT stojanovicjovica zn186cd014ohvo4
AT karanovicljiljana zn186cd014ohvo4

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