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(Z)-3-Diethylamino-6-({2-[(E)-4-(diethylamino)-2-hydroxybenzylideneamino]-4,5-dimethylphenyl}aminomethylidene)cyclohexa-2,4-dienone–5,5′-bis(diethylamino)-2,2′-[4,5-dimethyl-o-phenylenebis(nitrilomethylidyne)]diphenol
The asymmetric unit of the title Schiff base compound, C(30)H(38)N(4)O(2), comprises two crystallographically independent molecules, A and B. The structure is non-merohedrally twinned with a refined BASF ratio of 0.219 (6):0.701 (6). Molecule B shows both phenol–imine and keto–amine tautomeric for...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011455/ https://www.ncbi.nlm.nih.gov/pubmed/21589416 http://dx.doi.org/10.1107/S1600536810045290 |
Sumario: | The asymmetric unit of the title Schiff base compound, C(30)H(38)N(4)O(2), comprises two crystallographically independent molecules, A and B. The structure is non-merohedrally twinned with a refined BASF ratio of 0.219 (6):0.701 (6). Molecule B shows both phenol–imine and keto–amine tautomeric forms in a single structure. The dihedral angles between the central ring and the two outer rings are 5.9 (3) and 48.4 (3)° in molecule A, and 48.3 (3) and 6.9 (3)° in molecule B. Strong intramolecular O—H⋯N and N—H⋯O hydrogen bonds generate S(6) ring motifs. The crystal structure is further stabilized by intermolecular C—H⋯O, C—H⋯π and π–π interactions [centroid–centroid distances = 3.870 (4)–3.871 (4) Å]. |
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