Cargando…

{2,2′-[1,1′-(Ethane-1,2-diyldinitrilo)­diethyl­idyne]diphenolato}bis­(pyrrolidine)cobalt(III) perchlorate p-xylene hemisolvate

In the mononuclear title complex, [Co(C(18)H(18)N(2)O(2))(C(4)H(9)N)(2)]ClO(4)·0.5C(8)H(10), the Co(III) ion has a slightly distorted octa­hedral coordination geometry. In the Me–salen ligand, the benzene rings are almost parallel, making a dihedral angle of 0.48 (13)°, but the torsion angle along t...

Descripción completa

Detalles Bibliográficos
Autores principales: Salehi, Mehdi, Dutkiewicz, Grzegorz, Kubicki, Maciej
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011456/
https://www.ncbi.nlm.nih.gov/pubmed/21589274
http://dx.doi.org/10.1107/S160053681004660X
_version_ 1782194945243742208
author Salehi, Mehdi
Dutkiewicz, Grzegorz
Kubicki, Maciej
author_facet Salehi, Mehdi
Dutkiewicz, Grzegorz
Kubicki, Maciej
author_sort Salehi, Mehdi
collection PubMed
description In the mononuclear title complex, [Co(C(18)H(18)N(2)O(2))(C(4)H(9)N)(2)]ClO(4)·0.5C(8)H(10), the Co(III) ion has a slightly distorted octa­hedral coordination geometry. In the Me–salen ligand, the benzene rings are almost parallel, making a dihedral angle of 0.48 (13)°, but the torsion angle along the central C—C bond is 41.1 (2)°·The pyrrolidine rings are in slightly distorted chair conformations. The N atoms of the pyrrolidine axial ligands are involved in N—H⋯O hydrogen bonds with the perchlorate anions, and these hydrogen bonds connect the ionic species into infinite chains along the b axis. Some relatively short C—H⋯π inter­actions are also present in the crystal structure and C—H⋯O inter­actions occur. The guest solvent p-xylene mol­ecule lies on a special position at the inversion centre.
format Text
id pubmed-3011456
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30114562010-12-30 {2,2′-[1,1′-(Ethane-1,2-diyldinitrilo)­diethyl­idyne]diphenolato}bis­(pyrrolidine)cobalt(III) perchlorate p-xylene hemisolvate Salehi, Mehdi Dutkiewicz, Grzegorz Kubicki, Maciej Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Co(C(18)H(18)N(2)O(2))(C(4)H(9)N)(2)]ClO(4)·0.5C(8)H(10), the Co(III) ion has a slightly distorted octa­hedral coordination geometry. In the Me–salen ligand, the benzene rings are almost parallel, making a dihedral angle of 0.48 (13)°, but the torsion angle along the central C—C bond is 41.1 (2)°·The pyrrolidine rings are in slightly distorted chair conformations. The N atoms of the pyrrolidine axial ligands are involved in N—H⋯O hydrogen bonds with the perchlorate anions, and these hydrogen bonds connect the ionic species into infinite chains along the b axis. Some relatively short C—H⋯π inter­actions are also present in the crystal structure and C—H⋯O inter­actions occur. The guest solvent p-xylene mol­ecule lies on a special position at the inversion centre. International Union of Crystallography 2010-11-17 /pmc/articles/PMC3011456/ /pubmed/21589274 http://dx.doi.org/10.1107/S160053681004660X Text en © Salehi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Salehi, Mehdi
Dutkiewicz, Grzegorz
Kubicki, Maciej
{2,2′-[1,1′-(Ethane-1,2-diyldinitrilo)­diethyl­idyne]diphenolato}bis­(pyrrolidine)cobalt(III) perchlorate p-xylene hemisolvate
title {2,2′-[1,1′-(Ethane-1,2-diyldinitrilo)­diethyl­idyne]diphenolato}bis­(pyrrolidine)cobalt(III) perchlorate p-xylene hemisolvate
title_full {2,2′-[1,1′-(Ethane-1,2-diyldinitrilo)­diethyl­idyne]diphenolato}bis­(pyrrolidine)cobalt(III) perchlorate p-xylene hemisolvate
title_fullStr {2,2′-[1,1′-(Ethane-1,2-diyldinitrilo)­diethyl­idyne]diphenolato}bis­(pyrrolidine)cobalt(III) perchlorate p-xylene hemisolvate
title_full_unstemmed {2,2′-[1,1′-(Ethane-1,2-diyldinitrilo)­diethyl­idyne]diphenolato}bis­(pyrrolidine)cobalt(III) perchlorate p-xylene hemisolvate
title_short {2,2′-[1,1′-(Ethane-1,2-diyldinitrilo)­diethyl­idyne]diphenolato}bis­(pyrrolidine)cobalt(III) perchlorate p-xylene hemisolvate
title_sort {2,2′-[1,1′-(ethane-1,2-diyldinitrilo)­diethyl­idyne]diphenolato}bis­(pyrrolidine)cobalt(iii) perchlorate p-xylene hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011456/
https://www.ncbi.nlm.nih.gov/pubmed/21589274
http://dx.doi.org/10.1107/S160053681004660X
work_keys_str_mv AT salehimehdi 2211ethane12diyldinitrilodiethylidynediphenolatobispyrrolidinecobaltiiiperchloratepxylenehemisolvate
AT dutkiewiczgrzegorz 2211ethane12diyldinitrilodiethylidynediphenolatobispyrrolidinecobaltiiiperchloratepxylenehemisolvate
AT kubickimaciej 2211ethane12diyldinitrilodiethylidynediphenolatobispyrrolidinecobaltiiiperchloratepxylenehemisolvate