Cargando…
Bis(2,6-dihydroxybenzoato-κ(2) O (1),O (1′))(nitrato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)dysprosium(III)
In the mononuclear title complex, [Dy(C(7)H(5)O(4))(2)(NO(3))(C(12)H(8)N(2))(2)], the Dy(III) atom is in a distorted bicapped square-antiprismatic geometry formed by four N atoms from two chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2,6-dihydroxybenzoate (DHB) ligands and t...
| Autores principales: | , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011458/ https://www.ncbi.nlm.nih.gov/pubmed/21589319 http://dx.doi.org/10.1107/S1600536810048348 |
| _version_ | 1782194945816264704 |
|---|---|
| author | Dong, Weiqin Cai, Yaling Hong, Bo Jin, Hongxiao |
| author_facet | Dong, Weiqin Cai, Yaling Hong, Bo Jin, Hongxiao |
| author_sort | Dong, Weiqin |
| collection | PubMed |
| description | In the mononuclear title complex, [Dy(C(7)H(5)O(4))(2)(NO(3))(C(12)H(8)N(2))(2)], the Dy(III) atom is in a distorted bicapped square-antiprismatic geometry formed by four N atoms from two chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2,6-dihydroxybenzoate (DHB) ligands and two O atoms from a nitrate anion. Intermolecular π–π stacking interactions between the phen and DHB ligands [centroid–centroid distances = 3.542 (4) and 3.879 (4) Å] and between the pyridine and benzene rings of adjacent phen ligands [centroid–centroid distance = 3.751 (4) Å] stabilize the crystal structure. Intramolecular O–H⋯O hydrogen bonds are observed in the DHB ligands. |
| format | Text |
| id | pubmed-3011458 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30114582010-12-30 Bis(2,6-dihydroxybenzoato-κ(2) O (1),O (1′))(nitrato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)dysprosium(III) Dong, Weiqin Cai, Yaling Hong, Bo Jin, Hongxiao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Dy(C(7)H(5)O(4))(2)(NO(3))(C(12)H(8)N(2))(2)], the Dy(III) atom is in a distorted bicapped square-antiprismatic geometry formed by four N atoms from two chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2,6-dihydroxybenzoate (DHB) ligands and two O atoms from a nitrate anion. Intermolecular π–π stacking interactions between the phen and DHB ligands [centroid–centroid distances = 3.542 (4) and 3.879 (4) Å] and between the pyridine and benzene rings of adjacent phen ligands [centroid–centroid distance = 3.751 (4) Å] stabilize the crystal structure. Intramolecular O–H⋯O hydrogen bonds are observed in the DHB ligands. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011458/ /pubmed/21589319 http://dx.doi.org/10.1107/S1600536810048348 Text en © Dong et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Dong, Weiqin Cai, Yaling Hong, Bo Jin, Hongxiao Bis(2,6-dihydroxybenzoato-κ(2) O (1),O (1′))(nitrato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)dysprosium(III) |
| title | Bis(2,6-dihydroxybenzoato-κ(2)
O
(1),O
(1′))(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)dysprosium(III) |
| title_full | Bis(2,6-dihydroxybenzoato-κ(2)
O
(1),O
(1′))(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)dysprosium(III) |
| title_fullStr | Bis(2,6-dihydroxybenzoato-κ(2)
O
(1),O
(1′))(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)dysprosium(III) |
| title_full_unstemmed | Bis(2,6-dihydroxybenzoato-κ(2)
O
(1),O
(1′))(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)dysprosium(III) |
| title_short | Bis(2,6-dihydroxybenzoato-κ(2)
O
(1),O
(1′))(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)dysprosium(III) |
| title_sort | bis(2,6-dihydroxybenzoato-κ(2)
o
(1),o
(1′))(nitrato-κ(2)
o,o′)bis(1,10-phenanthroline-κ(2)
n,n′)dysprosium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011458/ https://www.ncbi.nlm.nih.gov/pubmed/21589319 http://dx.doi.org/10.1107/S1600536810048348 |
| work_keys_str_mv | AT dongweiqin bis26dihydroxybenzoatok2o1o1nitratok2oobis110phenanthrolinek2nndysprosiumiii AT caiyaling bis26dihydroxybenzoatok2o1o1nitratok2oobis110phenanthrolinek2nndysprosiumiii AT hongbo bis26dihydroxybenzoatok2o1o1nitratok2oobis110phenanthrolinek2nndysprosiumiii AT jinhongxiao bis26dihydroxybenzoatok2o1o1nitratok2oobis110phenanthrolinek2nndysprosiumiii |