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Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ(2) N (3):N (3′)]diformatomanganese(II)]
In the title compound, [Mn(CHO(2))(2)(C(12)H(10)N(4))(2)](n), the Mn(II) atom and the benzene ring of the ligand lie on an inversion centers. The Mn(II) atom has an octahedral coordination environment composed of four N atoms from two different symmetry-related N-heterocyclic ligands forming the ba...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011459/ https://www.ncbi.nlm.nih.gov/pubmed/21589210 http://dx.doi.org/10.1107/S1600536810044053 |
| _version_ | 1782194946189557760 |
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| author | Chen, Shui-Sheng Yang, Sen-Lin Zhang, Shu-Ping Lu, Zi-Qiang |
| author_facet | Chen, Shui-Sheng Yang, Sen-Lin Zhang, Shu-Ping Lu, Zi-Qiang |
| author_sort | Chen, Shui-Sheng |
| collection | PubMed |
| description | In the title compound, [Mn(CHO(2))(2)(C(12)H(10)N(4))(2)](n), the Mn(II) atom and the benzene ring of the ligand lie on an inversion centers. The Mn(II) atom has an octahedral coordination environment composed of four N atoms from two different symmetry-related N-heterocyclic ligands forming the basal plane, and two O atoms from symmetry-related formate anions occupying the apical positions. The title compound forms a two-dimensional (4,4) net parallel to (100) with all the Mn(II) atoms lying on a plane. The crystal structure is consolidated by intermolecular N—H⋯O hydrogen bonds.. |
| format | Text |
| id | pubmed-3011459 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30114592010-12-30 Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ(2) N (3):N (3′)]diformatomanganese(II)] Chen, Shui-Sheng Yang, Sen-Lin Zhang, Shu-Ping Lu, Zi-Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(CHO(2))(2)(C(12)H(10)N(4))(2)](n), the Mn(II) atom and the benzene ring of the ligand lie on an inversion centers. The Mn(II) atom has an octahedral coordination environment composed of four N atoms from two different symmetry-related N-heterocyclic ligands forming the basal plane, and two O atoms from symmetry-related formate anions occupying the apical positions. The title compound forms a two-dimensional (4,4) net parallel to (100) with all the Mn(II) atoms lying on a plane. The crystal structure is consolidated by intermolecular N—H⋯O hydrogen bonds.. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011459/ /pubmed/21589210 http://dx.doi.org/10.1107/S1600536810044053 Text en © Chen et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Shui-Sheng Yang, Sen-Lin Zhang, Shu-Ping Lu, Zi-Qiang Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ(2) N (3):N (3′)]diformatomanganese(II)] |
| title | Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ(2)
N
(3):N
(3′)]diformatomanganese(II)] |
| title_full | Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ(2)
N
(3):N
(3′)]diformatomanganese(II)] |
| title_fullStr | Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ(2)
N
(3):N
(3′)]diformatomanganese(II)] |
| title_full_unstemmed | Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ(2)
N
(3):N
(3′)]diformatomanganese(II)] |
| title_short | Poly[bis[μ-1,4-bis(1H-imidazol-5-yl)benzene-κ(2)
N
(3):N
(3′)]diformatomanganese(II)] |
| title_sort | poly[bis[μ-1,4-bis(1h-imidazol-5-yl)benzene-κ(2)
n
(3):n
(3′)]diformatomanganese(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011459/ https://www.ncbi.nlm.nih.gov/pubmed/21589210 http://dx.doi.org/10.1107/S1600536810044053 |
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