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4-Anilino-3-nitro-N-phenylbenzamide
In the title compound, C(19)H(15)N(3)O(3), the anilino and benzamide rings make dihedral angles of 10.66 (16) and 50.39 (16)°, respectively, with the nitro-substituted benzene ring. The nitro group is slightly twisted by 11.49 (17)° with respect to the attached benzene ring. There is an intramolecu...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011462/ https://www.ncbi.nlm.nih.gov/pubmed/21589566 http://dx.doi.org/10.1107/S1600536810043849 |
Sumario: | In the title compound, C(19)H(15)N(3)O(3), the anilino and benzamide rings make dihedral angles of 10.66 (16) and 50.39 (16)°, respectively, with the nitro-substituted benzene ring. The nitro group is slightly twisted by 11.49 (17)° with respect to the attached benzene ring. There is an intramolecular N—H⋯O hydrogen bond forming an S(6) ring. In the crystal, weak intermolecular N—H⋯O and C—H⋯O hydrogen bonds link the molecules into a chain parallel to the b axis. Futhermore, weak slipped π–π interactions [centroid–centroid distance = 3.819 (2) Å, interplanar distance = 3.567 Å and offset angle [how is the offset angle defined?] = 21°] between the anilino ring and its symmetry-related counterpart may help to stabilize the packing. |
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