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Tetraaqua(2,2′-bipyridine-κ(2) N,N′)magnesium(II) bis(4-fluorobenzoate)
The title compound, [Mg(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(4)FO(2))(2), consists of a bivalent [Mg(C(10)H(8)N(2))(H(2)O)(4)](2+) cation and two 4-fluorbenzoate anions. In the complex cation, the Mg(II) atom is coordinated by two N atoms from a 2,2′-bipyridine ligand and four water O atoms in a distorte...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011464/ https://www.ncbi.nlm.nih.gov/pubmed/21589298 http://dx.doi.org/10.1107/S1600536810047690 |
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author | Zhang, Bi-Song Qiu, Jian-Ping Liu, Li-Hua Xu, Wei |
author_facet | Zhang, Bi-Song Qiu, Jian-Ping Liu, Li-Hua Xu, Wei |
author_sort | Zhang, Bi-Song |
collection | PubMed |
description | The title compound, [Mg(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(4)FO(2))(2), consists of a bivalent [Mg(C(10)H(8)N(2))(H(2)O)(4)](2+) cation and two 4-fluorbenzoate anions. In the complex cation, the Mg(II) atom is coordinated by two N atoms from a 2,2′-bipyridine ligand and four water O atoms in a distorted MgN(2)O(4) octahedral geometry. The Mg(II) atom is located on a twofold rotation axis and thus a cation exhibits C (2) molecular symmetry. The 2,2′-bipyridine ligands exhibit nearly perfect planarity (r.m.s. deviations = 0.0061 Å). In the crystal, O—H⋯O and C—H⋯O hydrogen bonds link the cations and anions into a three-dimensional supramolecular network. |
format | Text |
id | pubmed-3011464 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30114642010-12-30 Tetraaqua(2,2′-bipyridine-κ(2) N,N′)magnesium(II) bis(4-fluorobenzoate) Zhang, Bi-Song Qiu, Jian-Ping Liu, Li-Hua Xu, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mg(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(4)FO(2))(2), consists of a bivalent [Mg(C(10)H(8)N(2))(H(2)O)(4)](2+) cation and two 4-fluorbenzoate anions. In the complex cation, the Mg(II) atom is coordinated by two N atoms from a 2,2′-bipyridine ligand and four water O atoms in a distorted MgN(2)O(4) octahedral geometry. The Mg(II) atom is located on a twofold rotation axis and thus a cation exhibits C (2) molecular symmetry. The 2,2′-bipyridine ligands exhibit nearly perfect planarity (r.m.s. deviations = 0.0061 Å). In the crystal, O—H⋯O and C—H⋯O hydrogen bonds link the cations and anions into a three-dimensional supramolecular network. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011464/ /pubmed/21589298 http://dx.doi.org/10.1107/S1600536810047690 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Bi-Song Qiu, Jian-Ping Liu, Li-Hua Xu, Wei Tetraaqua(2,2′-bipyridine-κ(2) N,N′)magnesium(II) bis(4-fluorobenzoate) |
title | Tetraaqua(2,2′-bipyridine-κ(2)
N,N′)magnesium(II) bis(4-fluorobenzoate) |
title_full | Tetraaqua(2,2′-bipyridine-κ(2)
N,N′)magnesium(II) bis(4-fluorobenzoate) |
title_fullStr | Tetraaqua(2,2′-bipyridine-κ(2)
N,N′)magnesium(II) bis(4-fluorobenzoate) |
title_full_unstemmed | Tetraaqua(2,2′-bipyridine-κ(2)
N,N′)magnesium(II) bis(4-fluorobenzoate) |
title_short | Tetraaqua(2,2′-bipyridine-κ(2)
N,N′)magnesium(II) bis(4-fluorobenzoate) |
title_sort | tetraaqua(2,2′-bipyridine-κ(2)
n,n′)magnesium(ii) bis(4-fluorobenzoate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011464/ https://www.ncbi.nlm.nih.gov/pubmed/21589298 http://dx.doi.org/10.1107/S1600536810047690 |
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