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Tetra­aqua­(2,2′-bipyridine-κ(2) N,N′)magnesium(II) bis­(4-fluoro­benzoate)

The title compound, [Mg(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(4)FO(2))(2), consists of a bivalent [Mg(C(10)H(8)N(2))(H(2)O)(4)](2+) cation and two 4-fluorbenzoate anions. In the complex cation, the Mg(II) atom is coordinated by two N atoms from a 2,2′-bipyridine ligand and four water O atoms in a distorte...

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Detalles Bibliográficos
Autores principales: Zhang, Bi-Song, Qiu, Jian-Ping, Liu, Li-Hua, Xu, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011464/
https://www.ncbi.nlm.nih.gov/pubmed/21589298
http://dx.doi.org/10.1107/S1600536810047690
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author Zhang, Bi-Song
Qiu, Jian-Ping
Liu, Li-Hua
Xu, Wei
author_facet Zhang, Bi-Song
Qiu, Jian-Ping
Liu, Li-Hua
Xu, Wei
author_sort Zhang, Bi-Song
collection PubMed
description The title compound, [Mg(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(4)FO(2))(2), consists of a bivalent [Mg(C(10)H(8)N(2))(H(2)O)(4)](2+) cation and two 4-fluorbenzoate anions. In the complex cation, the Mg(II) atom is coordinated by two N atoms from a 2,2′-bipyridine ligand and four water O atoms in a distorted MgN(2)O(4) octa­hedral geometry. The Mg(II) atom is located on a twofold rotation axis and thus a cation exhibits C (2) mol­ecular symmetry. The 2,2′-bipyridine ligands exhibit nearly perfect planarity (r.m.s. deviations = 0.0061 Å). In the crystal, O—H⋯O and C—H⋯O hydrogen bonds link the cations and anions into a three-dimensional supra­molecular network.
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spelling pubmed-30114642010-12-30 Tetra­aqua­(2,2′-bipyridine-κ(2) N,N′)magnesium(II) bis­(4-fluoro­benzoate) Zhang, Bi-Song Qiu, Jian-Ping Liu, Li-Hua Xu, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mg(C(10)H(8)N(2))(H(2)O)(4)](C(7)H(4)FO(2))(2), consists of a bivalent [Mg(C(10)H(8)N(2))(H(2)O)(4)](2+) cation and two 4-fluorbenzoate anions. In the complex cation, the Mg(II) atom is coordinated by two N atoms from a 2,2′-bipyridine ligand and four water O atoms in a distorted MgN(2)O(4) octa­hedral geometry. The Mg(II) atom is located on a twofold rotation axis and thus a cation exhibits C (2) mol­ecular symmetry. The 2,2′-bipyridine ligands exhibit nearly perfect planarity (r.m.s. deviations = 0.0061 Å). In the crystal, O—H⋯O and C—H⋯O hydrogen bonds link the cations and anions into a three-dimensional supra­molecular network. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011464/ /pubmed/21589298 http://dx.doi.org/10.1107/S1600536810047690 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Bi-Song
Qiu, Jian-Ping
Liu, Li-Hua
Xu, Wei
Tetra­aqua­(2,2′-bipyridine-κ(2) N,N′)magnesium(II) bis­(4-fluoro­benzoate)
title Tetra­aqua­(2,2′-bipyridine-κ(2) N,N′)magnesium(II) bis­(4-fluoro­benzoate)
title_full Tetra­aqua­(2,2′-bipyridine-κ(2) N,N′)magnesium(II) bis­(4-fluoro­benzoate)
title_fullStr Tetra­aqua­(2,2′-bipyridine-κ(2) N,N′)magnesium(II) bis­(4-fluoro­benzoate)
title_full_unstemmed Tetra­aqua­(2,2′-bipyridine-κ(2) N,N′)magnesium(II) bis­(4-fluoro­benzoate)
title_short Tetra­aqua­(2,2′-bipyridine-κ(2) N,N′)magnesium(II) bis­(4-fluoro­benzoate)
title_sort tetra­aqua­(2,2′-bipyridine-κ(2) n,n′)magnesium(ii) bis­(4-fluoro­benzoate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011464/
https://www.ncbi.nlm.nih.gov/pubmed/21589298
http://dx.doi.org/10.1107/S1600536810047690
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