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Diaqua­bis­[4-(dimethyl­amino)­benzoato-κO]bis­(nicotinamide-κN (1))zinc(II) dihydrate

In the centrosymmetric title structure, [Zn(C(9)H(10)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)]·2H(2)O, the Zn(II) cation, located on an inversion center, is coordinated by two 4-(methyl­amino)­benzoate anions, two nicotinamide ligands and two water mol­ecules in a slightly distorted octa­hedral geometr...

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Detalles Bibliográficos
Autores principales: Hökelek, Tuncer, Sağlam, Ertuğrul Gazi, Tercan, Barış, Aybirdi, Özgür, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011468/
https://www.ncbi.nlm.nih.gov/pubmed/21589309
http://dx.doi.org/10.1107/S1600536810046854
Descripción
Sumario:In the centrosymmetric title structure, [Zn(C(9)H(10)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)]·2H(2)O, the Zn(II) cation, located on an inversion center, is coordinated by two 4-(methyl­amino)­benzoate anions, two nicotinamide ligands and two water mol­ecules in a slightly distorted octa­hedral geometry. The dihedral angle between the carboxyl­ate group and the attached benzene ring is 3.09 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 77.10 (4)°. The uncoordinated water mol­ecule is linked to nicotinamide ligands by O—H⋯O hydrogen bonds. In the crystal, inter­molecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. A weak N—H⋯π inter­action also occurs.