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Diaqua­bis­[4-(dimethyl­amino)­benzoato-κO]bis­(nicotinamide-κN (1))zinc(II) dihydrate

In the centrosymmetric title structure, [Zn(C(9)H(10)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)]·2H(2)O, the Zn(II) cation, located on an inversion center, is coordinated by two 4-(methyl­amino)­benzoate anions, two nicotinamide ligands and two water mol­ecules in a slightly distorted octa­hedral geometr...

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Autores principales: Hökelek, Tuncer, Sağlam, Ertuğrul Gazi, Tercan, Barış, Aybirdi, Özgür, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011468/
https://www.ncbi.nlm.nih.gov/pubmed/21589309
http://dx.doi.org/10.1107/S1600536810046854
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author Hökelek, Tuncer
Sağlam, Ertuğrul Gazi
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Sağlam, Ertuğrul Gazi
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description In the centrosymmetric title structure, [Zn(C(9)H(10)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)]·2H(2)O, the Zn(II) cation, located on an inversion center, is coordinated by two 4-(methyl­amino)­benzoate anions, two nicotinamide ligands and two water mol­ecules in a slightly distorted octa­hedral geometry. The dihedral angle between the carboxyl­ate group and the attached benzene ring is 3.09 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 77.10 (4)°. The uncoordinated water mol­ecule is linked to nicotinamide ligands by O—H⋯O hydrogen bonds. In the crystal, inter­molecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. A weak N—H⋯π inter­action also occurs.
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spelling pubmed-30114682010-12-30 Diaqua­bis­[4-(dimethyl­amino)­benzoato-κO]bis­(nicotinamide-κN (1))zinc(II) dihydrate Hökelek, Tuncer Sağlam, Ertuğrul Gazi Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title structure, [Zn(C(9)H(10)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)]·2H(2)O, the Zn(II) cation, located on an inversion center, is coordinated by two 4-(methyl­amino)­benzoate anions, two nicotinamide ligands and two water mol­ecules in a slightly distorted octa­hedral geometry. The dihedral angle between the carboxyl­ate group and the attached benzene ring is 3.09 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 77.10 (4)°. The uncoordinated water mol­ecule is linked to nicotinamide ligands by O—H⋯O hydrogen bonds. In the crystal, inter­molecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. A weak N—H⋯π inter­action also occurs. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011468/ /pubmed/21589309 http://dx.doi.org/10.1107/S1600536810046854 Text en © Hökelek et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Sağlam, Ertuğrul Gazi
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
Diaqua­bis­[4-(dimethyl­amino)­benzoato-κO]bis­(nicotinamide-κN (1))zinc(II) dihydrate
title Diaqua­bis­[4-(dimethyl­amino)­benzoato-κO]bis­(nicotinamide-κN (1))zinc(II) dihydrate
title_full Diaqua­bis­[4-(dimethyl­amino)­benzoato-κO]bis­(nicotinamide-κN (1))zinc(II) dihydrate
title_fullStr Diaqua­bis­[4-(dimethyl­amino)­benzoato-κO]bis­(nicotinamide-κN (1))zinc(II) dihydrate
title_full_unstemmed Diaqua­bis­[4-(dimethyl­amino)­benzoato-κO]bis­(nicotinamide-κN (1))zinc(II) dihydrate
title_short Diaqua­bis­[4-(dimethyl­amino)­benzoato-κO]bis­(nicotinamide-κN (1))zinc(II) dihydrate
title_sort diaqua­bis­[4-(dimethyl­amino)­benzoato-κo]bis­(nicotinamide-κn (1))zinc(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011468/
https://www.ncbi.nlm.nih.gov/pubmed/21589309
http://dx.doi.org/10.1107/S1600536810046854
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