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Diaquabis[4-(dimethylamino)benzoato-κO]bis(nicotinamide-κN (1))zinc(II) dihydrate
In the centrosymmetric title structure, [Zn(C(9)H(10)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)]·2H(2)O, the Zn(II) cation, located on an inversion center, is coordinated by two 4-(methylamino)benzoate anions, two nicotinamide ligands and two water molecules in a slightly distorted octahedral geometr...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011468/ https://www.ncbi.nlm.nih.gov/pubmed/21589309 http://dx.doi.org/10.1107/S1600536810046854 |
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author | Hökelek, Tuncer Sağlam, Ertuğrul Gazi Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali |
author_facet | Hökelek, Tuncer Sağlam, Ertuğrul Gazi Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali |
author_sort | Hökelek, Tuncer |
collection | PubMed |
description | In the centrosymmetric title structure, [Zn(C(9)H(10)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)]·2H(2)O, the Zn(II) cation, located on an inversion center, is coordinated by two 4-(methylamino)benzoate anions, two nicotinamide ligands and two water molecules in a slightly distorted octahedral geometry. The dihedral angle between the carboxylate group and the attached benzene ring is 3.09 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 77.10 (4)°. The uncoordinated water molecule is linked to nicotinamide ligands by O—H⋯O hydrogen bonds. In the crystal, intermolecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. A weak N—H⋯π interaction also occurs. |
format | Text |
id | pubmed-3011468 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30114682010-12-30 Diaquabis[4-(dimethylamino)benzoato-κO]bis(nicotinamide-κN (1))zinc(II) dihydrate Hökelek, Tuncer Sağlam, Ertuğrul Gazi Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title structure, [Zn(C(9)H(10)NO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)]·2H(2)O, the Zn(II) cation, located on an inversion center, is coordinated by two 4-(methylamino)benzoate anions, two nicotinamide ligands and two water molecules in a slightly distorted octahedral geometry. The dihedral angle between the carboxylate group and the attached benzene ring is 3.09 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 77.10 (4)°. The uncoordinated water molecule is linked to nicotinamide ligands by O—H⋯O hydrogen bonds. In the crystal, intermolecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. A weak N—H⋯π interaction also occurs. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011468/ /pubmed/21589309 http://dx.doi.org/10.1107/S1600536810046854 Text en © Hökelek et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hökelek, Tuncer Sağlam, Ertuğrul Gazi Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Diaquabis[4-(dimethylamino)benzoato-κO]bis(nicotinamide-κN (1))zinc(II) dihydrate |
title | Diaquabis[4-(dimethylamino)benzoato-κO]bis(nicotinamide-κN
(1))zinc(II) dihydrate |
title_full | Diaquabis[4-(dimethylamino)benzoato-κO]bis(nicotinamide-κN
(1))zinc(II) dihydrate |
title_fullStr | Diaquabis[4-(dimethylamino)benzoato-κO]bis(nicotinamide-κN
(1))zinc(II) dihydrate |
title_full_unstemmed | Diaquabis[4-(dimethylamino)benzoato-κO]bis(nicotinamide-κN
(1))zinc(II) dihydrate |
title_short | Diaquabis[4-(dimethylamino)benzoato-κO]bis(nicotinamide-κN
(1))zinc(II) dihydrate |
title_sort | diaquabis[4-(dimethylamino)benzoato-κo]bis(nicotinamide-κn
(1))zinc(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011468/ https://www.ncbi.nlm.nih.gov/pubmed/21589309 http://dx.doi.org/10.1107/S1600536810046854 |
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