Cargando…
11-[(E)-Benzylidene]-14-hydroxy-8-phenyl-3,13-diazaheptacyclo[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetracosa-1(22),15,17,19(23),20-pentaen-10-one
In the title compound, C(35)H(30)N(2)O(2), the piperidine ring adopts a chair conformation and the pyrrolidine ring adopts an envelope conformation. The naphthalene ring makes dihedral angles of 24.56 (3) and 36.13 (4)° with the terminal phenyl rings. The dihedral angle between the two terminal phen...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011470/ https://www.ncbi.nlm.nih.gov/pubmed/21589358 http://dx.doi.org/10.1107/S1600536810043874 |
Sumario: | In the title compound, C(35)H(30)N(2)O(2), the piperidine ring adopts a chair conformation and the pyrrolidine ring adopts an envelope conformation. The naphthalene ring makes dihedral angles of 24.56 (3) and 36.13 (4)° with the terminal phenyl rings. The dihedral angle between the two terminal phenyl rings is 55.27 (5)°. One of the C atoms in the pyrrolidine ring is disordered over two sites, with a refined occupany ratio of 0.670 (3):0.330 (3). An intramolecular O—H⋯N hydrogen bond generates an S(6) ring. In the crystal structure, inversion dimers linked by pairs of C—H⋯O hydrogen bonds generate R (2) (2)(18) loops within sheets of molecules lying parallel to the bc plane. |
---|