11-[(E)-Benzyl­idene]-14-hy­droxy-8-phenyl-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one

In the title compound, C(35)H(30)N(2)O(2), the piperidine ring adopts a chair conformation and the pyrrolidine ring adopts an envelope conformation. The naphthalene ring makes dihedral angles of 24.56 (3) and 36.13 (4)° with the terminal phenyl rings. The dihedral angle between the two terminal phen...

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Autores principales: Kumar, Raju Suresh, Osman, Hasnah, Abdul Rahim, Aisyah Saad, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011470/
https://www.ncbi.nlm.nih.gov/pubmed/21589358
http://dx.doi.org/10.1107/S1600536810043874
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author Kumar, Raju Suresh
Osman, Hasnah
Abdul Rahim, Aisyah Saad
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Kumar, Raju Suresh
Osman, Hasnah
Abdul Rahim, Aisyah Saad
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Kumar, Raju Suresh
collection PubMed
description In the title compound, C(35)H(30)N(2)O(2), the piperidine ring adopts a chair conformation and the pyrrolidine ring adopts an envelope conformation. The naphthalene ring makes dihedral angles of 24.56 (3) and 36.13 (4)° with the terminal phenyl rings. The dihedral angle between the two terminal phenyl rings is 55.27 (5)°. One of the C atoms in the pyrrolidine ring is disordered over two sites, with a refined occupany ratio of 0.670 (3):0.330 (3). An intra­molecular O—H⋯N hydrogen bond generates an S(6) ring. In the crystal structure, inversion dimers linked by pairs of C—H⋯O hydrogen bonds generate R (2) (2)(18) loops within sheets of mol­ecules lying parallel to the bc plane.
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spelling pubmed-30114702010-12-30 11-[(E)-Benzyl­idene]-14-hy­droxy-8-phenyl-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one Kumar, Raju Suresh Osman, Hasnah Abdul Rahim, Aisyah Saad Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(35)H(30)N(2)O(2), the piperidine ring adopts a chair conformation and the pyrrolidine ring adopts an envelope conformation. The naphthalene ring makes dihedral angles of 24.56 (3) and 36.13 (4)° with the terminal phenyl rings. The dihedral angle between the two terminal phenyl rings is 55.27 (5)°. One of the C atoms in the pyrrolidine ring is disordered over two sites, with a refined occupany ratio of 0.670 (3):0.330 (3). An intra­molecular O—H⋯N hydrogen bond generates an S(6) ring. In the crystal structure, inversion dimers linked by pairs of C—H⋯O hydrogen bonds generate R (2) (2)(18) loops within sheets of mol­ecules lying parallel to the bc plane. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011470/ /pubmed/21589358 http://dx.doi.org/10.1107/S1600536810043874 Text en © Kumar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kumar, Raju Suresh
Osman, Hasnah
Abdul Rahim, Aisyah Saad
Hemamalini, Madhukar
Fun, Hoong-Kun
11-[(E)-Benzyl­idene]-14-hy­droxy-8-phenyl-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one
title 11-[(E)-Benzyl­idene]-14-hy­droxy-8-phenyl-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one
title_full 11-[(E)-Benzyl­idene]-14-hy­droxy-8-phenyl-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one
title_fullStr 11-[(E)-Benzyl­idene]-14-hy­droxy-8-phenyl-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one
title_full_unstemmed 11-[(E)-Benzyl­idene]-14-hy­droxy-8-phenyl-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one
title_short 11-[(E)-Benzyl­idene]-14-hy­droxy-8-phenyl-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one
title_sort 11-[(e)-benzyl­idene]-14-hy­droxy-8-phenyl-3,13-diaza­hepta­cyclo­[13.7.1.1(9,13).0(2,9).0(2,14).0(3,7).0(19,23)]tetra­cosa-1(22),15,17,19(23),20-pentaen-10-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011470/
https://www.ncbi.nlm.nih.gov/pubmed/21589358
http://dx.doi.org/10.1107/S1600536810043874
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