N-[(1S,2S)-2-Amino-1,2-diphenyl­eth­yl]-4-methyl­benzene­sulfonamide [(S,S)-TsDPEN]

The crystal structure of the title compound, C(21)H(22)N(2)O(2)S, shows a network of N—H⋯N and N—H⋯O hydrogen bonds. The tolyl and 1-phenyl rings are almost mutually coplanar [7.89 (9)°], while the 2-phenyl ring makes a dihedral angle of 50.8 (1) ° with the 1-phenyl ring. An intra­molecular N—H⋯N hy...

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Detalles Bibliográficos
Autores principales: Schlemmer, Claudine, Schollmeyer, Dieter, Blank, Nancy, Stoye, Alexander, Opatz, Till
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011471/
https://www.ncbi.nlm.nih.gov/pubmed/21589615
http://dx.doi.org/10.1107/S1600536810049159
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author Schlemmer, Claudine
Schollmeyer, Dieter
Blank, Nancy
Stoye, Alexander
Opatz, Till
author_facet Schlemmer, Claudine
Schollmeyer, Dieter
Blank, Nancy
Stoye, Alexander
Opatz, Till
author_sort Schlemmer, Claudine
collection PubMed
description The crystal structure of the title compound, C(21)H(22)N(2)O(2)S, shows a network of N—H⋯N and N—H⋯O hydrogen bonds. The tolyl and 1-phenyl rings are almost mutually coplanar [7.89 (9)°], while the 2-phenyl ring makes a dihedral angle of 50.8 (1) ° with the 1-phenyl ring. An intra­molecular N—H⋯N hydrogen bond stabilizes the mol­ecular conformation.
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spelling pubmed-30114712010-12-30 N-[(1S,2S)-2-Amino-1,2-diphenyl­eth­yl]-4-methyl­benzene­sulfonamide [(S,S)-TsDPEN] Schlemmer, Claudine Schollmeyer, Dieter Blank, Nancy Stoye, Alexander Opatz, Till Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(21)H(22)N(2)O(2)S, shows a network of N—H⋯N and N—H⋯O hydrogen bonds. The tolyl and 1-phenyl rings are almost mutually coplanar [7.89 (9)°], while the 2-phenyl ring makes a dihedral angle of 50.8 (1) ° with the 1-phenyl ring. An intra­molecular N—H⋯N hydrogen bond stabilizes the mol­ecular conformation. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011471/ /pubmed/21589615 http://dx.doi.org/10.1107/S1600536810049159 Text en © Schlemmer et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Schlemmer, Claudine
Schollmeyer, Dieter
Blank, Nancy
Stoye, Alexander
Opatz, Till
N-[(1S,2S)-2-Amino-1,2-diphenyl­eth­yl]-4-methyl­benzene­sulfonamide [(S,S)-TsDPEN]
title N-[(1S,2S)-2-Amino-1,2-diphenyl­eth­yl]-4-methyl­benzene­sulfonamide [(S,S)-TsDPEN]
title_full N-[(1S,2S)-2-Amino-1,2-diphenyl­eth­yl]-4-methyl­benzene­sulfonamide [(S,S)-TsDPEN]
title_fullStr N-[(1S,2S)-2-Amino-1,2-diphenyl­eth­yl]-4-methyl­benzene­sulfonamide [(S,S)-TsDPEN]
title_full_unstemmed N-[(1S,2S)-2-Amino-1,2-diphenyl­eth­yl]-4-methyl­benzene­sulfonamide [(S,S)-TsDPEN]
title_short N-[(1S,2S)-2-Amino-1,2-diphenyl­eth­yl]-4-methyl­benzene­sulfonamide [(S,S)-TsDPEN]
title_sort n-[(1s,2s)-2-amino-1,2-diphenyl­eth­yl]-4-methyl­benzene­sulfonamide [(s,s)-tsdpen]
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011471/
https://www.ncbi.nlm.nih.gov/pubmed/21589615
http://dx.doi.org/10.1107/S1600536810049159
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