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Bis[tetraaqua(1,10-phenanthroline-κ(2) N,N′)cobalt(II)] hexaaquacobalt(II) bis[3,5-bis(carboxylatomethoxy)benzoate] tetrahydrate
The title compound, [Co(C(12)H(8)N(2))(H(2)O)(4)](2)[Co(H(2)O)(6)](C(11)H(7)O(8))(2)·4H(2)O, was obtanied by the reaction of cobalt acetate with 3,5-bis(carboxymethoxy)benzoic acid and 1,10-phenanthroline. The asymmetric unit contains one tetraaqua(1,10-phenanthroline)cobalt(II) cation, one ha...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011475/ https://www.ncbi.nlm.nih.gov/pubmed/21589263 http://dx.doi.org/10.1107/S1600536810046386 |
Sumario: | The title compound, [Co(C(12)H(8)N(2))(H(2)O)(4)](2)[Co(H(2)O)(6)](C(11)H(7)O(8))(2)·4H(2)O, was obtanied by the reaction of cobalt acetate with 3,5-bis(carboxymethoxy)benzoic acid and 1,10-phenanthroline. The asymmetric unit contains one tetraaqua(1,10-phenanthroline)cobalt(II) cation, one half of a hexaaquacobalt(II) cation that is completed by inversion symmetry, one 3,5-bis(carboxylatomethoxy)benzoate trianion and two lattice water molecules. The two Co(II) atoms each show a slightly distorted octahedral coordination (CoO(6) and CoO(4)N(2)). The cations, anions and lattice water molecules are linked by an intricate network of O—H⋯O hydrogen bonds into a three-dimensional structure. |
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