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Bis[tetraaqua(1,10-phenanthroline-κ(2) N,N′)cobalt(II)] hexaaquacobalt(II) bis[3,5-bis(carboxylatomethoxy)benzoate] tetrahydrate
The title compound, [Co(C(12)H(8)N(2))(H(2)O)(4)](2)[Co(H(2)O)(6)](C(11)H(7)O(8))(2)·4H(2)O, was obtanied by the reaction of cobalt acetate with 3,5-bis(carboxymethoxy)benzoic acid and 1,10-phenanthroline. The asymmetric unit contains one tetraaqua(1,10-phenanthroline)cobalt(II) cation, one ha...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011475/ https://www.ncbi.nlm.nih.gov/pubmed/21589263 http://dx.doi.org/10.1107/S1600536810046386 |
| _version_ | 1782194950488719360 |
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| author | Song, Hui-Ying Wang, Xiao-Juan Qiu, Shi-Zhen Feng, Yun-Long |
| author_facet | Song, Hui-Ying Wang, Xiao-Juan Qiu, Shi-Zhen Feng, Yun-Long |
| author_sort | Song, Hui-Ying |
| collection | PubMed |
| description | The title compound, [Co(C(12)H(8)N(2))(H(2)O)(4)](2)[Co(H(2)O)(6)](C(11)H(7)O(8))(2)·4H(2)O, was obtanied by the reaction of cobalt acetate with 3,5-bis(carboxymethoxy)benzoic acid and 1,10-phenanthroline. The asymmetric unit contains one tetraaqua(1,10-phenanthroline)cobalt(II) cation, one half of a hexaaquacobalt(II) cation that is completed by inversion symmetry, one 3,5-bis(carboxylatomethoxy)benzoate trianion and two lattice water molecules. The two Co(II) atoms each show a slightly distorted octahedral coordination (CoO(6) and CoO(4)N(2)). The cations, anions and lattice water molecules are linked by an intricate network of O—H⋯O hydrogen bonds into a three-dimensional structure. |
| format | Text |
| id | pubmed-3011475 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30114752010-12-30 Bis[tetraaqua(1,10-phenanthroline-κ(2) N,N′)cobalt(II)] hexaaquacobalt(II) bis[3,5-bis(carboxylatomethoxy)benzoate] tetrahydrate Song, Hui-Ying Wang, Xiao-Juan Qiu, Shi-Zhen Feng, Yun-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(12)H(8)N(2))(H(2)O)(4)](2)[Co(H(2)O)(6)](C(11)H(7)O(8))(2)·4H(2)O, was obtanied by the reaction of cobalt acetate with 3,5-bis(carboxymethoxy)benzoic acid and 1,10-phenanthroline. The asymmetric unit contains one tetraaqua(1,10-phenanthroline)cobalt(II) cation, one half of a hexaaquacobalt(II) cation that is completed by inversion symmetry, one 3,5-bis(carboxylatomethoxy)benzoate trianion and two lattice water molecules. The two Co(II) atoms each show a slightly distorted octahedral coordination (CoO(6) and CoO(4)N(2)). The cations, anions and lattice water molecules are linked by an intricate network of O—H⋯O hydrogen bonds into a three-dimensional structure. International Union of Crystallography 2010-11-17 /pmc/articles/PMC3011475/ /pubmed/21589263 http://dx.doi.org/10.1107/S1600536810046386 Text en © Song et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Song, Hui-Ying Wang, Xiao-Juan Qiu, Shi-Zhen Feng, Yun-Long Bis[tetraaqua(1,10-phenanthroline-κ(2) N,N′)cobalt(II)] hexaaquacobalt(II) bis[3,5-bis(carboxylatomethoxy)benzoate] tetrahydrate |
| title | Bis[tetraaqua(1,10-phenanthroline-κ(2)
N,N′)cobalt(II)] hexaaquacobalt(II) bis[3,5-bis(carboxylatomethoxy)benzoate] tetrahydrate |
| title_full | Bis[tetraaqua(1,10-phenanthroline-κ(2)
N,N′)cobalt(II)] hexaaquacobalt(II) bis[3,5-bis(carboxylatomethoxy)benzoate] tetrahydrate |
| title_fullStr | Bis[tetraaqua(1,10-phenanthroline-κ(2)
N,N′)cobalt(II)] hexaaquacobalt(II) bis[3,5-bis(carboxylatomethoxy)benzoate] tetrahydrate |
| title_full_unstemmed | Bis[tetraaqua(1,10-phenanthroline-κ(2)
N,N′)cobalt(II)] hexaaquacobalt(II) bis[3,5-bis(carboxylatomethoxy)benzoate] tetrahydrate |
| title_short | Bis[tetraaqua(1,10-phenanthroline-κ(2)
N,N′)cobalt(II)] hexaaquacobalt(II) bis[3,5-bis(carboxylatomethoxy)benzoate] tetrahydrate |
| title_sort | bis[tetraaqua(1,10-phenanthroline-κ(2)
n,n′)cobalt(ii)] hexaaquacobalt(ii) bis[3,5-bis(carboxylatomethoxy)benzoate] tetrahydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011475/ https://www.ncbi.nlm.nih.gov/pubmed/21589263 http://dx.doi.org/10.1107/S1600536810046386 |
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