Dipotassium tetra­aqua­bis­[3,5-bis­(dicyano­methyl­ene)cyclo­pentane-1,2,4-trionato(1−)-κN]cobaltate(II)

The title structure, K(2)[Co(C(11)N(4)O(3))(2)(H(2)O)(4)], is isotypic with K(2)[Fe(C(11)N(4)O(3))(2)(H(2)O)(4)]. The Co(II) atom is in a distorted octa­hedral CoN(2)O(4) geometry, forming a dianionic mononuclear entity. Each dianionic unit is associated with two potassium cations and inter­acts wit...

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Autores principales: Chagas, Luciano Honorato, Janczak, Jan, Machado, Flavia C., de Oliveira, Luiz Fernando C., Diniz, Renata
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011486/
https://www.ncbi.nlm.nih.gov/pubmed/21589332
http://dx.doi.org/10.1107/S1600536810048646
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author Chagas, Luciano Honorato
Janczak, Jan
Machado, Flavia C.
de Oliveira, Luiz Fernando C.
Diniz, Renata
author_facet Chagas, Luciano Honorato
Janczak, Jan
Machado, Flavia C.
de Oliveira, Luiz Fernando C.
Diniz, Renata
author_sort Chagas, Luciano Honorato
collection PubMed
description The title structure, K(2)[Co(C(11)N(4)O(3))(2)(H(2)O)(4)], is isotypic with K(2)[Fe(C(11)N(4)O(3))(2)(H(2)O)(4)]. The Co(II) atom is in a distorted octa­hedral CoN(2)O(4) geometry, forming a dianionic mononuclear entity. Each dianionic unit is associated with two potassium cations and inter­acts with adjacent units through O—H⋯N and O—H⋯O hydrogen bonds.
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spelling pubmed-30114862010-12-30 Dipotassium tetra­aqua­bis­[3,5-bis­(dicyano­methyl­ene)cyclo­pentane-1,2,4-trionato(1−)-κN]cobaltate(II) Chagas, Luciano Honorato Janczak, Jan Machado, Flavia C. de Oliveira, Luiz Fernando C. Diniz, Renata Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title structure, K(2)[Co(C(11)N(4)O(3))(2)(H(2)O)(4)], is isotypic with K(2)[Fe(C(11)N(4)O(3))(2)(H(2)O)(4)]. The Co(II) atom is in a distorted octa­hedral CoN(2)O(4) geometry, forming a dianionic mononuclear entity. Each dianionic unit is associated with two potassium cations and inter­acts with adjacent units through O—H⋯N and O—H⋯O hydrogen bonds. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011486/ /pubmed/21589332 http://dx.doi.org/10.1107/S1600536810048646 Text en © Chagas et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chagas, Luciano Honorato
Janczak, Jan
Machado, Flavia C.
de Oliveira, Luiz Fernando C.
Diniz, Renata
Dipotassium tetra­aqua­bis­[3,5-bis­(dicyano­methyl­ene)cyclo­pentane-1,2,4-trionato(1−)-κN]cobaltate(II)
title Dipotassium tetra­aqua­bis­[3,5-bis­(dicyano­methyl­ene)cyclo­pentane-1,2,4-trionato(1−)-κN]cobaltate(II)
title_full Dipotassium tetra­aqua­bis­[3,5-bis­(dicyano­methyl­ene)cyclo­pentane-1,2,4-trionato(1−)-κN]cobaltate(II)
title_fullStr Dipotassium tetra­aqua­bis­[3,5-bis­(dicyano­methyl­ene)cyclo­pentane-1,2,4-trionato(1−)-κN]cobaltate(II)
title_full_unstemmed Dipotassium tetra­aqua­bis­[3,5-bis­(dicyano­methyl­ene)cyclo­pentane-1,2,4-trionato(1−)-κN]cobaltate(II)
title_short Dipotassium tetra­aqua­bis­[3,5-bis­(dicyano­methyl­ene)cyclo­pentane-1,2,4-trionato(1−)-κN]cobaltate(II)
title_sort dipotassium tetra­aqua­bis­[3,5-bis­(dicyano­methyl­ene)cyclo­pentane-1,2,4-trionato(1−)-κn]cobaltate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011486/
https://www.ncbi.nlm.nih.gov/pubmed/21589332
http://dx.doi.org/10.1107/S1600536810048646
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