[2-Hydroxy-N′-(4-oxo-4-phenyl­butan-2-yl­idene)benzohydrazidato(2−)]pyridine­copper(II)

The mononuclear title complex, [Cu(C(17)H(14)N(2)O(3))(C(5)H(5)N)], was synthesized by the reaction of CuCl(2)·2H(2)O with N-(4-oxo-4-phenyl­butan-2-yl­idene)benzohydrazide (H(2) L). The central Cu(II) atom exhibits a distorted square-planar coordination geometry, defined by two O atoms, one N atom...

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Detalles Bibliográficos
Autores principales: Zhang, Shu-Ping, Wei, Ying, Shao, Si-Chang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011487/
https://www.ncbi.nlm.nih.gov/pubmed/21589308
http://dx.doi.org/10.1107/S1600536810047719
Descripción
Sumario:The mononuclear title complex, [Cu(C(17)H(14)N(2)O(3))(C(5)H(5)N)], was synthesized by the reaction of CuCl(2)·2H(2)O with N-(4-oxo-4-phenyl­butan-2-yl­idene)benzohydrazide (H(2) L). The central Cu(II) atom exhibits a distorted square-planar coordination geometry, defined by two O atoms, one N atom from the ligand and one pyridine N atom with Cu—N distances of 1.874 (4) and 1.963 (4) Å, while the Cu—O distances are 1.857 (3) and 1.890 (3) Å. An intra­molecular O—H⋯N inter­action occurs.

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