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Bis(2,6-dihy­droxy­benzoato-κ(2) O (1) ,O (1′))(nitrato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)europium(III)

The title mononuclear complex, [Eu(C(7)H(5)O(3))(2)(NO(3))(C(12)H(8)N(2))(2)], is isostructural with those of other lanthanides. The Eu atom is in a pseudo-bicapped square-anti­prismatic geometry, formed by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and by six O atoms, four f...

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Detalles Bibliográficos
Autores principales: Huang, Bao, Chiya, Wang, Xinqing, Wang, Jin, Hongxiao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011488/
https://www.ncbi.nlm.nih.gov/pubmed/21589289
http://dx.doi.org/10.1107/S1600536810047148
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author Huang, Bao
Chiya, Wang
Xinqing, Wang
Jin, Hongxiao
author_facet Huang, Bao
Chiya, Wang
Xinqing, Wang
Jin, Hongxiao
author_sort Huang, Bao
collection PubMed
description The title mononuclear complex, [Eu(C(7)H(5)O(3))(2)(NO(3))(C(12)H(8)N(2))(2)], is isostructural with those of other lanthanides. The Eu atom is in a pseudo-bicapped square-anti­prismatic geometry, formed by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and by six O atoms, four from two 2,6-dihy­droxy­benzoate (DHB) ligands and the other two from a nitrate anion. π–π stacking inter­actions between phen and DHB ligands [centroid–centroid distances = 3.5312 (19) and 3.8347 (16) Å], and between phen and phen ligands [face-to-face separation = 3.433 (4) Å] of adjacent complexes stabilize the crystal structure. Intra­molecular O—H⋯O hydrogen bonds are observed in the DHB ligands.
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spelling pubmed-30114882010-12-30 Bis(2,6-dihy­droxy­benzoato-κ(2) O (1) ,O (1′))(nitrato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)europium(III) Huang, Bao Chiya, Wang Xinqing, Wang Jin, Hongxiao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mononuclear complex, [Eu(C(7)H(5)O(3))(2)(NO(3))(C(12)H(8)N(2))(2)], is isostructural with those of other lanthanides. The Eu atom is in a pseudo-bicapped square-anti­prismatic geometry, formed by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and by six O atoms, four from two 2,6-dihy­droxy­benzoate (DHB) ligands and the other two from a nitrate anion. π–π stacking inter­actions between phen and DHB ligands [centroid–centroid distances = 3.5312 (19) and 3.8347 (16) Å], and between phen and phen ligands [face-to-face separation = 3.433 (4) Å] of adjacent complexes stabilize the crystal structure. Intra­molecular O—H⋯O hydrogen bonds are observed in the DHB ligands. International Union of Crystallography 2010-11-20 /pmc/articles/PMC3011488/ /pubmed/21589289 http://dx.doi.org/10.1107/S1600536810047148 Text en © Huang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Bao
Chiya, Wang
Xinqing, Wang
Jin, Hongxiao
Bis(2,6-dihy­droxy­benzoato-κ(2) O (1) ,O (1′))(nitrato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)europium(III)
title Bis(2,6-dihy­droxy­benzoato-κ(2) O (1) ,O (1′))(nitrato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)europium(III)
title_full Bis(2,6-dihy­droxy­benzoato-κ(2) O (1) ,O (1′))(nitrato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)europium(III)
title_fullStr Bis(2,6-dihy­droxy­benzoato-κ(2) O (1) ,O (1′))(nitrato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)europium(III)
title_full_unstemmed Bis(2,6-dihy­droxy­benzoato-κ(2) O (1) ,O (1′))(nitrato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)europium(III)
title_short Bis(2,6-dihy­droxy­benzoato-κ(2) O (1) ,O (1′))(nitrato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)europium(III)
title_sort bis(2,6-dihy­droxy­benzoato-κ(2) o (1) ,o (1′))(nitrato-κ(2) o,o′)bis­(1,10-phenanthroline-κ(2) n,n′)europium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011488/
https://www.ncbi.nlm.nih.gov/pubmed/21589289
http://dx.doi.org/10.1107/S1600536810047148
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