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Bis(dicyclohexylammonium) μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis[aqua(oxalato-κ(2) O (1),O (2))diphenylstannate(IV)]
The structure of the title compound, (C(12)H(24)N)(2)[Sn(2)(C(6)H(5))(4)(C(2)O(4))(3)(H(2)O)(2)], consists of a bischelating oxalate ion, located on an inversion center, which is linked to two SnPh(2) groups. The coordination sphere of the Sn(IV) ion is completed by a monochelating oxalate anion and...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011489/ https://www.ncbi.nlm.nih.gov/pubmed/21589314 http://dx.doi.org/10.1107/S1600536810046738 |
| _version_ | 1782194954025566208 |
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| author | Gueye, Ndongo Diop, Libasse Molloy, K. C. Kieran Kociok-Köhn, Gabrielle |
| author_facet | Gueye, Ndongo Diop, Libasse Molloy, K. C. Kieran Kociok-Köhn, Gabrielle |
| author_sort | Gueye, Ndongo |
| collection | PubMed |
| description | The structure of the title compound, (C(12)H(24)N)(2)[Sn(2)(C(6)H(5))(4)(C(2)O(4))(3)(H(2)O)(2)], consists of a bischelating oxalate ion, located on an inversion center, which is linked to two SnPh(2) groups. The coordination sphere of the Sn(IV) ion is completed by a monochelating oxalate anion and a water molecule. The Sn(IV) atoms are thus seven-coordinated. The discrete binuclear units are further connected by hydrogen bonds, leading to a supramolecular crystal structure. The asymmetric unit contains one half dianion and one (Cy(2)NH(2))(+) cation. |
| format | Text |
| id | pubmed-3011489 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30114892010-12-30 Bis(dicyclohexylammonium) μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis[aqua(oxalato-κ(2) O (1),O (2))diphenylstannate(IV)] Gueye, Ndongo Diop, Libasse Molloy, K. C. Kieran Kociok-Köhn, Gabrielle Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, (C(12)H(24)N)(2)[Sn(2)(C(6)H(5))(4)(C(2)O(4))(3)(H(2)O)(2)], consists of a bischelating oxalate ion, located on an inversion center, which is linked to two SnPh(2) groups. The coordination sphere of the Sn(IV) ion is completed by a monochelating oxalate anion and a water molecule. The Sn(IV) atoms are thus seven-coordinated. The discrete binuclear units are further connected by hydrogen bonds, leading to a supramolecular crystal structure. The asymmetric unit contains one half dianion and one (Cy(2)NH(2))(+) cation. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011489/ /pubmed/21589314 http://dx.doi.org/10.1107/S1600536810046738 Text en © Gueye et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gueye, Ndongo Diop, Libasse Molloy, K. C. Kieran Kociok-Köhn, Gabrielle Bis(dicyclohexylammonium) μ-oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis[aqua(oxalato-κ(2) O (1),O (2))diphenylstannate(IV)] |
| title | Bis(dicyclohexylammonium) μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis[aqua(oxalato-κ(2)
O
(1),O
(2))diphenylstannate(IV)] |
| title_full | Bis(dicyclohexylammonium) μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis[aqua(oxalato-κ(2)
O
(1),O
(2))diphenylstannate(IV)] |
| title_fullStr | Bis(dicyclohexylammonium) μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis[aqua(oxalato-κ(2)
O
(1),O
(2))diphenylstannate(IV)] |
| title_full_unstemmed | Bis(dicyclohexylammonium) μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis[aqua(oxalato-κ(2)
O
(1),O
(2))diphenylstannate(IV)] |
| title_short | Bis(dicyclohexylammonium) μ-oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis[aqua(oxalato-κ(2)
O
(1),O
(2))diphenylstannate(IV)] |
| title_sort | bis(dicyclohexylammonium) μ-oxalato-κ(4)
o
(1),o
(2):o
(1′),o
(2′)-bis[aqua(oxalato-κ(2)
o
(1),o
(2))diphenylstannate(iv)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011489/ https://www.ncbi.nlm.nih.gov/pubmed/21589314 http://dx.doi.org/10.1107/S1600536810046738 |
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