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Bis[μ-4-(methyl­amino)­benzoato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­[4-(methyl­amino)­benzoato-κ(2) O,O′](nicotinamide-κN)cadmium(II)}

In the dinuclear centrosymmetric Cd(II) compound, [Cd(2)(C(8)H(8)NO(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the metal atom is chelated by two carboxyl­ate groups from 4-(methyl­amino)­benzoate (PMAB) anions, and coordinated by one nicotinamide and one water mol­ecule; a carboxyl­ate O atom from the adj...

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Autores principales: Hökelek, Tuncer, Sağlam, Ertuğrul Gazi, Tercan, Barış, Aybirdi, Özgür, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011491/
https://www.ncbi.nlm.nih.gov/pubmed/21589250
http://dx.doi.org/10.1107/S1600536810046258
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author Hökelek, Tuncer
Sağlam, Ertuğrul Gazi
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Sağlam, Ertuğrul Gazi
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description In the dinuclear centrosymmetric Cd(II) compound, [Cd(2)(C(8)H(8)NO(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the metal atom is chelated by two carboxyl­ate groups from 4-(methyl­amino)­benzoate (PMAB) anions, and coordinated by one nicotinamide and one water mol­ecule; a carboxyl­ate O atom from the adjacent PMAB anion bridges to the Cd atom, completing the irregular seven-coordination geometry. In the crystal, inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. π–π contacts between the pyridine rings [centroid–centroid distance = 3.965 (1) Å] may further stabilize the structure. A weak C—H⋯π inter­action also occurs.
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spelling pubmed-30114912010-12-30 Bis[μ-4-(methyl­amino)­benzoato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­[4-(methyl­amino)­benzoato-κ(2) O,O′](nicotinamide-κN)cadmium(II)} Hökelek, Tuncer Sağlam, Ertuğrul Gazi Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the dinuclear centrosymmetric Cd(II) compound, [Cd(2)(C(8)H(8)NO(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the metal atom is chelated by two carboxyl­ate groups from 4-(methyl­amino)­benzoate (PMAB) anions, and coordinated by one nicotinamide and one water mol­ecule; a carboxyl­ate O atom from the adjacent PMAB anion bridges to the Cd atom, completing the irregular seven-coordination geometry. In the crystal, inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. π–π contacts between the pyridine rings [centroid–centroid distance = 3.965 (1) Å] may further stabilize the structure. A weak C—H⋯π inter­action also occurs. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011491/ /pubmed/21589250 http://dx.doi.org/10.1107/S1600536810046258 Text en © Hökelek et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Sağlam, Ertuğrul Gazi
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
Bis[μ-4-(methyl­amino)­benzoato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­[4-(methyl­amino)­benzoato-κ(2) O,O′](nicotinamide-κN)cadmium(II)}
title Bis[μ-4-(methyl­amino)­benzoato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­[4-(methyl­amino)­benzoato-κ(2) O,O′](nicotinamide-κN)cadmium(II)}
title_full Bis[μ-4-(methyl­amino)­benzoato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­[4-(methyl­amino)­benzoato-κ(2) O,O′](nicotinamide-κN)cadmium(II)}
title_fullStr Bis[μ-4-(methyl­amino)­benzoato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­[4-(methyl­amino)­benzoato-κ(2) O,O′](nicotinamide-κN)cadmium(II)}
title_full_unstemmed Bis[μ-4-(methyl­amino)­benzoato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­[4-(methyl­amino)­benzoato-κ(2) O,O′](nicotinamide-κN)cadmium(II)}
title_short Bis[μ-4-(methyl­amino)­benzoato]-κ(3) O,O′:O;κ(3) O:O,O′-bis­{aqua­[4-(methyl­amino)­benzoato-κ(2) O,O′](nicotinamide-κN)cadmium(II)}
title_sort bis[μ-4-(methyl­amino)­benzoato]-κ(3) o,o′:o;κ(3) o:o,o′-bis­{aqua­[4-(methyl­amino)­benzoato-κ(2) o,o′](nicotinamide-κn)cadmium(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011491/
https://www.ncbi.nlm.nih.gov/pubmed/21589250
http://dx.doi.org/10.1107/S1600536810046258
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