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catena-Poly[[[diaqua(nitrato-κ(2) O,O′)cerium(III)]-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′] monohydrate]
In the title compound, {[Ce(C(8)H(7)O(3))(2)(NO(3))(H(2)O)(2)]·H(2)O}(n), the Ce(III) ion is coordinated by eight O atoms from four 2-(4-hydroxyphenyl)acetate (HPAA) ligands, two O atoms from the chelating nitrate anion and two water molecules in a distorted bis-capped quadrangular prismatic geo...
Autor principal: | |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011495/ https://www.ncbi.nlm.nih.gov/pubmed/21589283 http://dx.doi.org/10.1107/S1600536810047239 |
Sumario: | In the title compound, {[Ce(C(8)H(7)O(3))(2)(NO(3))(H(2)O)(2)]·H(2)O}(n), the Ce(III) ion is coordinated by eight O atoms from four 2-(4-hydroxyphenyl)acetate (HPAA) ligands, two O atoms from the chelating nitrate anion and two water molecules in a distorted bis-capped quadrangular prismatic geometry. The HPAA ligands coordinate in a bridging tridentate mode. In the crystal, intermolecular O—H⋯O hydrogen bonds form a three-dimensional network which consolidates the packing. |
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