Cargando…
catena-Poly[[[diaqua(nitrato-κ(2) O,O′)cerium(III)]-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′] monohydrate]
In the title compound, {[Ce(C(8)H(7)O(3))(2)(NO(3))(H(2)O)(2)]·H(2)O}(n), the Ce(III) ion is coordinated by eight O atoms from four 2-(4-hydroxyphenyl)acetate (HPAA) ligands, two O atoms from the chelating nitrate anion and two water molecules in a distorted bis-capped quadrangular prismatic geo...
| Autor principal: | |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011495/ https://www.ncbi.nlm.nih.gov/pubmed/21589283 http://dx.doi.org/10.1107/S1600536810047239 |
| _version_ | 1782194955482038272 |
|---|---|
| author | Guo, Hang-Ming |
| author_facet | Guo, Hang-Ming |
| author_sort | Guo, Hang-Ming |
| collection | PubMed |
| description | In the title compound, {[Ce(C(8)H(7)O(3))(2)(NO(3))(H(2)O)(2)]·H(2)O}(n), the Ce(III) ion is coordinated by eight O atoms from four 2-(4-hydroxyphenyl)acetate (HPAA) ligands, two O atoms from the chelating nitrate anion and two water molecules in a distorted bis-capped quadrangular prismatic geometry. The HPAA ligands coordinate in a bridging tridentate mode. In the crystal, intermolecular O—H⋯O hydrogen bonds form a three-dimensional network which consolidates the packing. |
| format | Text |
| id | pubmed-3011495 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30114952010-12-30 catena-Poly[[[diaqua(nitrato-κ(2) O,O′)cerium(III)]-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′] monohydrate] Guo, Hang-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Ce(C(8)H(7)O(3))(2)(NO(3))(H(2)O)(2)]·H(2)O}(n), the Ce(III) ion is coordinated by eight O atoms from four 2-(4-hydroxyphenyl)acetate (HPAA) ligands, two O atoms from the chelating nitrate anion and two water molecules in a distorted bis-capped quadrangular prismatic geometry. The HPAA ligands coordinate in a bridging tridentate mode. In the crystal, intermolecular O—H⋯O hydrogen bonds form a three-dimensional network which consolidates the packing. International Union of Crystallography 2010-11-20 /pmc/articles/PMC3011495/ /pubmed/21589283 http://dx.doi.org/10.1107/S1600536810047239 Text en © Hang-Ming Guo 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Guo, Hang-Ming catena-Poly[[[diaqua(nitrato-κ(2) O,O′)cerium(III)]-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3) O,O′:O;κ(3) O:O,O′] monohydrate] |
| title |
catena-Poly[[[diaqua(nitrato-κ(2)
O,O′)cerium(III)]-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′] monohydrate] |
| title_full |
catena-Poly[[[diaqua(nitrato-κ(2)
O,O′)cerium(III)]-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′] monohydrate] |
| title_fullStr |
catena-Poly[[[diaqua(nitrato-κ(2)
O,O′)cerium(III)]-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′] monohydrate] |
| title_full_unstemmed |
catena-Poly[[[diaqua(nitrato-κ(2)
O,O′)cerium(III)]-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′] monohydrate] |
| title_short |
catena-Poly[[[diaqua(nitrato-κ(2)
O,O′)cerium(III)]-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
O,O′:O;κ(3)
O:O,O′] monohydrate] |
| title_sort | catena-poly[[[diaqua(nitrato-κ(2)
o,o′)cerium(iii)]-bis[μ-2-(4-hydroxyphenyl)acetato]-κ(3)
o,o′:o;κ(3)
o:o,o′] monohydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011495/ https://www.ncbi.nlm.nih.gov/pubmed/21589283 http://dx.doi.org/10.1107/S1600536810047239 |
| work_keys_str_mv | AT guohangming catenapolydiaquanitratok2ooceriumiiibism24hydroxyphenylacetatok3oook3ooomonohydrate |