Diethyl 4-acetyl-5-(2-nitro­phen­yl)pyrrolidine-2,2-dicarboxyl­ate

The title compound, C(18)H(22)N(2)O(7), was synthesized by the 1,3-dipolar cyclo­addition reaction of but-3-en-2-one, diethyl 2-amino­malonate and 2-nitro­benzaldehyde. In the mol­ecule, the pyrrolidine ring possesses an envelope conformation. Inter­molecular N—H⋯O and C—H⋯O hydrogen bonds are prese...

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Detalles Bibliográficos
Autor principal: He, Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011499/
https://www.ncbi.nlm.nih.gov/pubmed/21589499
http://dx.doi.org/10.1107/S1600536810045691
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author He, Long
author_facet He, Long
author_sort He, Long
collection PubMed
description The title compound, C(18)H(22)N(2)O(7), was synthesized by the 1,3-dipolar cyclo­addition reaction of but-3-en-2-one, diethyl 2-amino­malonate and 2-nitro­benzaldehyde. In the mol­ecule, the pyrrolidine ring possesses an envelope conformation. Inter­molecular N—H⋯O and C—H⋯O hydrogen bonds are present in the crystal structure.
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spelling pubmed-30114992010-12-30 Diethyl 4-acetyl-5-(2-nitro­phen­yl)pyrrolidine-2,2-dicarboxyl­ate He, Long Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(22)N(2)O(7), was synthesized by the 1,3-dipolar cyclo­addition reaction of but-3-en-2-one, diethyl 2-amino­malonate and 2-nitro­benzaldehyde. In the mol­ecule, the pyrrolidine ring possesses an envelope conformation. Inter­molecular N—H⋯O and C—H⋯O hydrogen bonds are present in the crystal structure. International Union of Crystallography 2010-11-17 /pmc/articles/PMC3011499/ /pubmed/21589499 http://dx.doi.org/10.1107/S1600536810045691 Text en © Long He 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
He, Long
Diethyl 4-acetyl-5-(2-nitro­phen­yl)pyrrolidine-2,2-dicarboxyl­ate
title Diethyl 4-acetyl-5-(2-nitro­phen­yl)pyrrolidine-2,2-dicarboxyl­ate
title_full Diethyl 4-acetyl-5-(2-nitro­phen­yl)pyrrolidine-2,2-dicarboxyl­ate
title_fullStr Diethyl 4-acetyl-5-(2-nitro­phen­yl)pyrrolidine-2,2-dicarboxyl­ate
title_full_unstemmed Diethyl 4-acetyl-5-(2-nitro­phen­yl)pyrrolidine-2,2-dicarboxyl­ate
title_short Diethyl 4-acetyl-5-(2-nitro­phen­yl)pyrrolidine-2,2-dicarboxyl­ate
title_sort diethyl 4-acetyl-5-(2-nitro­phen­yl)pyrrolidine-2,2-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011499/
https://www.ncbi.nlm.nih.gov/pubmed/21589499
http://dx.doi.org/10.1107/S1600536810045691
work_keys_str_mv AT helong diethyl4acetyl52nitrophenylpyrrolidine22dicarboxylate

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