Tetra-μ(3)-tert-butano­lato-tetra­thallium(I)

The title compound, [Tl(4)(C(4)H(9)O)(4)], featuring a (Tl—O)(4) cube, crystallizes with a quarter-mol­ecule (located on a special position of site symmetry [Image: see text]..) and a half-mol­ecule (located on a special position of site symmetry 23.) in the asymmetric unit. The Tl—O bond distances...

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Detalles Bibliográficos
Autores principales: Blasberg, Florian, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011501/
https://www.ncbi.nlm.nih.gov/pubmed/21589296
http://dx.doi.org/10.1107/S1600536810047550
Descripción
Sumario:The title compound, [Tl(4)(C(4)H(9)O)(4)], featuring a (Tl—O)(4) cube, crystallizes with a quarter-mol­ecule (located on a special position of site symmetry [Image: see text]..) and a half-mol­ecule (located on a special position of site symmetry 23.) in the asymmetric unit. The Tl—O bond distances range from 2.463 (12) to 2.506 (12) Å. All O—Tl—O bond angles are smaller than 90° whereas the Tl—O—Tl angles are wider than a recta­ngular angle.

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