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Tetra-μ(3)-tert-butano­lato-tetra­thallium(I)

The title compound, [Tl(4)(C(4)H(9)O)(4)], featuring a (Tl—O)(4) cube, crystallizes with a quarter-mol­ecule (located on a special position of site symmetry [Image: see text]..) and a half-mol­ecule (located on a special position of site symmetry 23.) in the asymmetric unit. The Tl—O bond distances...

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Detalles Bibliográficos
Autores principales: Blasberg, Florian, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011501/
https://www.ncbi.nlm.nih.gov/pubmed/21589296
http://dx.doi.org/10.1107/S1600536810047550
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author Blasberg, Florian
Lerner, Hans-Wolfram
Bolte, Michael
author_facet Blasberg, Florian
Lerner, Hans-Wolfram
Bolte, Michael
author_sort Blasberg, Florian
collection PubMed
description The title compound, [Tl(4)(C(4)H(9)O)(4)], featuring a (Tl—O)(4) cube, crystallizes with a quarter-mol­ecule (located on a special position of site symmetry [Image: see text]..) and a half-mol­ecule (located on a special position of site symmetry 23.) in the asymmetric unit. The Tl—O bond distances range from 2.463 (12) to 2.506 (12) Å. All O—Tl—O bond angles are smaller than 90° whereas the Tl—O—Tl angles are wider than a recta­ngular angle.
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spelling pubmed-30115012010-12-30 Tetra-μ(3)-tert-butano­lato-tetra­thallium(I) Blasberg, Florian Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Tl(4)(C(4)H(9)O)(4)], featuring a (Tl—O)(4) cube, crystallizes with a quarter-mol­ecule (located on a special position of site symmetry [Image: see text]..) and a half-mol­ecule (located on a special position of site symmetry 23.) in the asymmetric unit. The Tl—O bond distances range from 2.463 (12) to 2.506 (12) Å. All O—Tl—O bond angles are smaller than 90° whereas the Tl—O—Tl angles are wider than a recta­ngular angle. International Union of Crystallography 2010-11-20 /pmc/articles/PMC3011501/ /pubmed/21589296 http://dx.doi.org/10.1107/S1600536810047550 Text en © Blasberg et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Blasberg, Florian
Lerner, Hans-Wolfram
Bolte, Michael
Tetra-μ(3)-tert-butano­lato-tetra­thallium(I)
title Tetra-μ(3)-tert-butano­lato-tetra­thallium(I)
title_full Tetra-μ(3)-tert-butano­lato-tetra­thallium(I)
title_fullStr Tetra-μ(3)-tert-butano­lato-tetra­thallium(I)
title_full_unstemmed Tetra-μ(3)-tert-butano­lato-tetra­thallium(I)
title_short Tetra-μ(3)-tert-butano­lato-tetra­thallium(I)
title_sort tetra-μ(3)-tert-butano­lato-tetra­thallium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011501/
https://www.ncbi.nlm.nih.gov/pubmed/21589296
http://dx.doi.org/10.1107/S1600536810047550
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