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Tetra-μ(3)-tert-butanolato-tetrathallium(I)
The title compound, [Tl(4)(C(4)H(9)O)(4)], featuring a (Tl—O)(4) cube, crystallizes with a quarter-molecule (located on a special position of site symmetry [Image: see text]..) and a half-molecule (located on a special position of site symmetry 23.) in the asymmetric unit. The Tl—O bond distances...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011501/ https://www.ncbi.nlm.nih.gov/pubmed/21589296 http://dx.doi.org/10.1107/S1600536810047550 |
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author | Blasberg, Florian Lerner, Hans-Wolfram Bolte, Michael |
author_facet | Blasberg, Florian Lerner, Hans-Wolfram Bolte, Michael |
author_sort | Blasberg, Florian |
collection | PubMed |
description | The title compound, [Tl(4)(C(4)H(9)O)(4)], featuring a (Tl—O)(4) cube, crystallizes with a quarter-molecule (located on a special position of site symmetry [Image: see text]..) and a half-molecule (located on a special position of site symmetry 23.) in the asymmetric unit. The Tl—O bond distances range from 2.463 (12) to 2.506 (12) Å. All O—Tl—O bond angles are smaller than 90° whereas the Tl—O—Tl angles are wider than a rectangular angle. |
format | Text |
id | pubmed-3011501 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30115012010-12-30 Tetra-μ(3)-tert-butanolato-tetrathallium(I) Blasberg, Florian Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Tl(4)(C(4)H(9)O)(4)], featuring a (Tl—O)(4) cube, crystallizes with a quarter-molecule (located on a special position of site symmetry [Image: see text]..) and a half-molecule (located on a special position of site symmetry 23.) in the asymmetric unit. The Tl—O bond distances range from 2.463 (12) to 2.506 (12) Å. All O—Tl—O bond angles are smaller than 90° whereas the Tl—O—Tl angles are wider than a rectangular angle. International Union of Crystallography 2010-11-20 /pmc/articles/PMC3011501/ /pubmed/21589296 http://dx.doi.org/10.1107/S1600536810047550 Text en © Blasberg et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Blasberg, Florian Lerner, Hans-Wolfram Bolte, Michael Tetra-μ(3)-tert-butanolato-tetrathallium(I) |
title | Tetra-μ(3)-tert-butanolato-tetrathallium(I) |
title_full | Tetra-μ(3)-tert-butanolato-tetrathallium(I) |
title_fullStr | Tetra-μ(3)-tert-butanolato-tetrathallium(I) |
title_full_unstemmed | Tetra-μ(3)-tert-butanolato-tetrathallium(I) |
title_short | Tetra-μ(3)-tert-butanolato-tetrathallium(I) |
title_sort | tetra-μ(3)-tert-butanolato-tetrathallium(i) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011501/ https://www.ncbi.nlm.nih.gov/pubmed/21589296 http://dx.doi.org/10.1107/S1600536810047550 |
work_keys_str_mv | AT blasbergflorian tetram3tertbutanolatotetrathalliumi AT lernerhanswolfram tetram3tertbutanolatotetrathalliumi AT boltemichael tetram3tertbutanolatotetrathalliumi |