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Poly[[hexaaqua(μ(2)-fumarato-κ(4) O (1),O (1′):O (4),O (4′))bis(μ(3)-maleato-κ(4) O (1),O (1′):O (4):O (4′))disamarium(III)] hexahydrate]
In the title coordination polymer, {[Sm(2)(C(4)H(2)O(4))(3)(H(2)O)(6)]·6H(2)O}(n), the Sm(III) ion is nine-coordinated by four O atoms from three different maleate ligands, two O atoms from one fumarate ligand and three O atoms from three water molecules. The fumarate ligand lies on an inversion ce...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011504/ https://www.ncbi.nlm.nih.gov/pubmed/21589236 http://dx.doi.org/10.1107/S1600536810045204 |
Sumario: | In the title coordination polymer, {[Sm(2)(C(4)H(2)O(4))(3)(H(2)O)(6)]·6H(2)O}(n), the Sm(III) ion is nine-coordinated by four O atoms from three different maleate ligands, two O atoms from one fumarate ligand and three O atoms from three water molecules. The fumarate ligand lies on an inversion center. Adjacent Sm(III) ions are bridged by the maleate and fumarate ligands, forming a layer parallel to (011). The layers are further linked by intermolecular O—H⋯O hydrogen bonds into a three-dimensional supramolecular network. |
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