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Poly[[hexaaqua(μ(2)-fumarato-κ(4) O (1),O (1′):O (4),O (4′))bis(μ(3)-maleato-κ(4) O (1),O (1′):O (4):O (4′))disamarium(III)] hexahydrate]
In the title coordination polymer, {[Sm(2)(C(4)H(2)O(4))(3)(H(2)O)(6)]·6H(2)O}(n), the Sm(III) ion is nine-coordinated by four O atoms from three different maleate ligands, two O atoms from one fumarate ligand and three O atoms from three water molecules. The fumarate ligand lies on an inversion ce...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011504/ https://www.ncbi.nlm.nih.gov/pubmed/21589236 http://dx.doi.org/10.1107/S1600536810045204 |
| _version_ | 1782194957619036160 |
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| author | Li, Bao Wu, Li-Xin |
| author_facet | Li, Bao Wu, Li-Xin |
| author_sort | Li, Bao |
| collection | PubMed |
| description | In the title coordination polymer, {[Sm(2)(C(4)H(2)O(4))(3)(H(2)O)(6)]·6H(2)O}(n), the Sm(III) ion is nine-coordinated by four O atoms from three different maleate ligands, two O atoms from one fumarate ligand and three O atoms from three water molecules. The fumarate ligand lies on an inversion center. Adjacent Sm(III) ions are bridged by the maleate and fumarate ligands, forming a layer parallel to (011). The layers are further linked by intermolecular O—H⋯O hydrogen bonds into a three-dimensional supramolecular network. |
| format | Text |
| id | pubmed-3011504 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30115042010-12-30 Poly[[hexaaqua(μ(2)-fumarato-κ(4) O (1),O (1′):O (4),O (4′))bis(μ(3)-maleato-κ(4) O (1),O (1′):O (4):O (4′))disamarium(III)] hexahydrate] Li, Bao Wu, Li-Xin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Sm(2)(C(4)H(2)O(4))(3)(H(2)O)(6)]·6H(2)O}(n), the Sm(III) ion is nine-coordinated by four O atoms from three different maleate ligands, two O atoms from one fumarate ligand and three O atoms from three water molecules. The fumarate ligand lies on an inversion center. Adjacent Sm(III) ions are bridged by the maleate and fumarate ligands, forming a layer parallel to (011). The layers are further linked by intermolecular O—H⋯O hydrogen bonds into a three-dimensional supramolecular network. International Union of Crystallography 2010-11-10 /pmc/articles/PMC3011504/ /pubmed/21589236 http://dx.doi.org/10.1107/S1600536810045204 Text en © Li and Wu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Bao Wu, Li-Xin Poly[[hexaaqua(μ(2)-fumarato-κ(4) O (1),O (1′):O (4),O (4′))bis(μ(3)-maleato-κ(4) O (1),O (1′):O (4):O (4′))disamarium(III)] hexahydrate] |
| title | Poly[[hexaaqua(μ(2)-fumarato-κ(4)
O
(1),O
(1′):O
(4),O
(4′))bis(μ(3)-maleato-κ(4)
O
(1),O
(1′):O
(4):O
(4′))disamarium(III)] hexahydrate] |
| title_full | Poly[[hexaaqua(μ(2)-fumarato-κ(4)
O
(1),O
(1′):O
(4),O
(4′))bis(μ(3)-maleato-κ(4)
O
(1),O
(1′):O
(4):O
(4′))disamarium(III)] hexahydrate] |
| title_fullStr | Poly[[hexaaqua(μ(2)-fumarato-κ(4)
O
(1),O
(1′):O
(4),O
(4′))bis(μ(3)-maleato-κ(4)
O
(1),O
(1′):O
(4):O
(4′))disamarium(III)] hexahydrate] |
| title_full_unstemmed | Poly[[hexaaqua(μ(2)-fumarato-κ(4)
O
(1),O
(1′):O
(4),O
(4′))bis(μ(3)-maleato-κ(4)
O
(1),O
(1′):O
(4):O
(4′))disamarium(III)] hexahydrate] |
| title_short | Poly[[hexaaqua(μ(2)-fumarato-κ(4)
O
(1),O
(1′):O
(4),O
(4′))bis(μ(3)-maleato-κ(4)
O
(1),O
(1′):O
(4):O
(4′))disamarium(III)] hexahydrate] |
| title_sort | poly[[hexaaqua(μ(2)-fumarato-κ(4)
o
(1),o
(1′):o
(4),o
(4′))bis(μ(3)-maleato-κ(4)
o
(1),o
(1′):o
(4):o
(4′))disamarium(iii)] hexahydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011504/ https://www.ncbi.nlm.nih.gov/pubmed/21589236 http://dx.doi.org/10.1107/S1600536810045204 |
| work_keys_str_mv | AT libao polyhexaaquam2fumaratok4o1o1o4o4bism3maleatok4o1o1o4o4disamariumiiihexahydrate AT wulixin polyhexaaquam2fumaratok4o1o1o4o4bism3maleatok4o1o1o4o4disamariumiiihexahydrate |