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(4-Chlorobenzohydrazidato-κ(2) N′,O)[2-(4-chlorobenzoylhydrazinylidene-κ(2) N (1),O)-3-phenylpropionato(2−)-κO (1)]oxidovanadium(V) methanol monosolvate
The V(V) atom in the title compound, [V(C(7)H(6)ClN(2)O)(C(16)H(11)ClN(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O′-chelated by the (benzoylhydrazinylidene)propionate dianion. The distorted octahedral trans-N(2)O(4) coordination geometry is completed by the vanad...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011505/ https://www.ncbi.nlm.nih.gov/pubmed/21589249 http://dx.doi.org/10.1107/S1600536810045678 |
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| author | Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng |
| author_facet | Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng |
| author_sort | Wong, Hon Wee |
| collection | PubMed |
| description | The V(V) atom in the title compound, [V(C(7)H(6)ClN(2)O)(C(16)H(11)ClN(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O′-chelated by the (benzoylhydrazinylidene)propionate dianion. The distorted octahedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. The mononuclear and solvent molecules are linked by N—H⋯O and O—H⋯O hydrogen bonds about a center of inversion, generating a dimer. |
| format | Text |
| id | pubmed-3011505 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30115052010-12-30 (4-Chlorobenzohydrazidato-κ(2) N′,O)[2-(4-chlorobenzoylhydrazinylidene-κ(2) N (1),O)-3-phenylpropionato(2−)-κO (1)]oxidovanadium(V) methanol monosolvate Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The V(V) atom in the title compound, [V(C(7)H(6)ClN(2)O)(C(16)H(11)ClN(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O′-chelated by the (benzoylhydrazinylidene)propionate dianion. The distorted octahedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. The mononuclear and solvent molecules are linked by N—H⋯O and O—H⋯O hydrogen bonds about a center of inversion, generating a dimer. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011505/ /pubmed/21589249 http://dx.doi.org/10.1107/S1600536810045678 Text en © Wong et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng (4-Chlorobenzohydrazidato-κ(2) N′,O)[2-(4-chlorobenzoylhydrazinylidene-κ(2) N (1),O)-3-phenylpropionato(2−)-κO (1)]oxidovanadium(V) methanol monosolvate |
| title | (4-Chlorobenzohydrazidato-κ(2)
N′,O)[2-(4-chlorobenzoylhydrazinylidene-κ(2)
N
(1),O)-3-phenylpropionato(2−)-κO
(1)]oxidovanadium(V) methanol monosolvate |
| title_full | (4-Chlorobenzohydrazidato-κ(2)
N′,O)[2-(4-chlorobenzoylhydrazinylidene-κ(2)
N
(1),O)-3-phenylpropionato(2−)-κO
(1)]oxidovanadium(V) methanol monosolvate |
| title_fullStr | (4-Chlorobenzohydrazidato-κ(2)
N′,O)[2-(4-chlorobenzoylhydrazinylidene-κ(2)
N
(1),O)-3-phenylpropionato(2−)-κO
(1)]oxidovanadium(V) methanol monosolvate |
| title_full_unstemmed | (4-Chlorobenzohydrazidato-κ(2)
N′,O)[2-(4-chlorobenzoylhydrazinylidene-κ(2)
N
(1),O)-3-phenylpropionato(2−)-κO
(1)]oxidovanadium(V) methanol monosolvate |
| title_short | (4-Chlorobenzohydrazidato-κ(2)
N′,O)[2-(4-chlorobenzoylhydrazinylidene-κ(2)
N
(1),O)-3-phenylpropionato(2−)-κO
(1)]oxidovanadium(V) methanol monosolvate |
| title_sort | (4-chlorobenzohydrazidato-κ(2)
n′,o)[2-(4-chlorobenzoylhydrazinylidene-κ(2)
n
(1),o)-3-phenylpropionato(2−)-κo
(1)]oxidovanadium(v) methanol monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011505/ https://www.ncbi.nlm.nih.gov/pubmed/21589249 http://dx.doi.org/10.1107/S1600536810045678 |
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