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Aqua[2-(3-carboxy-5-carboxylatophenoxy)acetato-κO (1)]bis(1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate
In the title complex, [Mn(C(10)H(6)O(7))(C(12)H(8)N(2))(2)(H(2)O)]·2H(2)O, the Mn(II) atom is coordinated by two O atoms from one 2-(3-carboxy-5-carboxylatophenoxy)acetate (HOABDC(2−)) dianion and one water molecule and by four N atoms from two 1,10-phenanthroline (phen) ligands within a distort...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011514/ https://www.ncbi.nlm.nih.gov/pubmed/21589312 http://dx.doi.org/10.1107/S1600536810048142 |
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author | Cai, Yi-Ni Chen, Jing Feng, Yun-Long |
author_facet | Cai, Yi-Ni Chen, Jing Feng, Yun-Long |
author_sort | Cai, Yi-Ni |
collection | PubMed |
description | In the title complex, [Mn(C(10)H(6)O(7))(C(12)H(8)N(2))(2)(H(2)O)]·2H(2)O, the Mn(II) atom is coordinated by two O atoms from one 2-(3-carboxy-5-carboxylatophenoxy)acetate (HOABDC(2−)) dianion and one water molecule and by four N atoms from two 1,10-phenanthroline (phen) ligands within a distorted octahedral geometry. O—H⋯O hydrogen bonding between –COOH and –COO(−) groups of adjacent molecules and between carboxylate groups and coordinated and uncoordinated water molecules leads to a three-dimensional structure which is further stabilized by weak π–π interactions of adjacent phen ligands with centroid–centroid separations of 4.2932 (1) Å. |
format | Text |
id | pubmed-3011514 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30115142010-12-30 Aqua[2-(3-carboxy-5-carboxylatophenoxy)acetato-κO (1)]bis(1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate Cai, Yi-Ni Chen, Jing Feng, Yun-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(10)H(6)O(7))(C(12)H(8)N(2))(2)(H(2)O)]·2H(2)O, the Mn(II) atom is coordinated by two O atoms from one 2-(3-carboxy-5-carboxylatophenoxy)acetate (HOABDC(2−)) dianion and one water molecule and by four N atoms from two 1,10-phenanthroline (phen) ligands within a distorted octahedral geometry. O—H⋯O hydrogen bonding between –COOH and –COO(−) groups of adjacent molecules and between carboxylate groups and coordinated and uncoordinated water molecules leads to a three-dimensional structure which is further stabilized by weak π–π interactions of adjacent phen ligands with centroid–centroid separations of 4.2932 (1) Å. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011514/ /pubmed/21589312 http://dx.doi.org/10.1107/S1600536810048142 Text en © Cai et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Cai, Yi-Ni Chen, Jing Feng, Yun-Long Aqua[2-(3-carboxy-5-carboxylatophenoxy)acetato-κO (1)]bis(1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate |
title | Aqua[2-(3-carboxy-5-carboxylatophenoxy)acetato-κO
(1)]bis(1,10-phenanthroline-κ(2)
N,N′)manganese(II) dihydrate |
title_full | Aqua[2-(3-carboxy-5-carboxylatophenoxy)acetato-κO
(1)]bis(1,10-phenanthroline-κ(2)
N,N′)manganese(II) dihydrate |
title_fullStr | Aqua[2-(3-carboxy-5-carboxylatophenoxy)acetato-κO
(1)]bis(1,10-phenanthroline-κ(2)
N,N′)manganese(II) dihydrate |
title_full_unstemmed | Aqua[2-(3-carboxy-5-carboxylatophenoxy)acetato-κO
(1)]bis(1,10-phenanthroline-κ(2)
N,N′)manganese(II) dihydrate |
title_short | Aqua[2-(3-carboxy-5-carboxylatophenoxy)acetato-κO
(1)]bis(1,10-phenanthroline-κ(2)
N,N′)manganese(II) dihydrate |
title_sort | aqua[2-(3-carboxy-5-carboxylatophenoxy)acetato-κo
(1)]bis(1,10-phenanthroline-κ(2)
n,n′)manganese(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011514/ https://www.ncbi.nlm.nih.gov/pubmed/21589312 http://dx.doi.org/10.1107/S1600536810048142 |
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