Cargando…

Aqua­[2-(3-carb­oxy-5-carboxyl­atophen­oxy)acetato-κO (1)]bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate

In the title complex, [Mn(C(10)H(6)O(7))(C(12)H(8)N(2))(2)(H(2)O)]·2H(2)O, the Mn(II) atom is coordinated by two O atoms from one 2-(3-carb­oxy-5-carboxyl­atophen­oxy)acetate (HOABDC(2−)) dianion and one water mol­ecule and by four N atoms from two 1,10-phenanthroline (phen) ligands within a distort...

Descripción completa

Detalles Bibliográficos
Autores principales: Cai, Yi-Ni, Chen, Jing, Feng, Yun-Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011514/
https://www.ncbi.nlm.nih.gov/pubmed/21589312
http://dx.doi.org/10.1107/S1600536810048142
_version_ 1782194960008740864
author Cai, Yi-Ni
Chen, Jing
Feng, Yun-Long
author_facet Cai, Yi-Ni
Chen, Jing
Feng, Yun-Long
author_sort Cai, Yi-Ni
collection PubMed
description In the title complex, [Mn(C(10)H(6)O(7))(C(12)H(8)N(2))(2)(H(2)O)]·2H(2)O, the Mn(II) atom is coordinated by two O atoms from one 2-(3-carb­oxy-5-carboxyl­atophen­oxy)acetate (HOABDC(2−)) dianion and one water mol­ecule and by four N atoms from two 1,10-phenanthroline (phen) ligands within a distorted octa­hedral geometry. O—H⋯O hydrogen bonding between –COOH and –COO(−) groups of adjacent mol­ecules and between carboxyl­ate groups and coordinated and uncoordin­ated water mol­ecules leads to a three-dimensional structure which is further stabilized by weak π–π inter­actions of adjacent phen ligands with centroid–centroid separations of 4.2932 (1) Å.
format Text
id pubmed-3011514
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30115142010-12-30 Aqua­[2-(3-carb­oxy-5-carboxyl­atophen­oxy)acetato-κO (1)]bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate Cai, Yi-Ni Chen, Jing Feng, Yun-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(10)H(6)O(7))(C(12)H(8)N(2))(2)(H(2)O)]·2H(2)O, the Mn(II) atom is coordinated by two O atoms from one 2-(3-carb­oxy-5-carboxyl­atophen­oxy)acetate (HOABDC(2−)) dianion and one water mol­ecule and by four N atoms from two 1,10-phenanthroline (phen) ligands within a distorted octa­hedral geometry. O—H⋯O hydrogen bonding between –COOH and –COO(−) groups of adjacent mol­ecules and between carboxyl­ate groups and coordinated and uncoordin­ated water mol­ecules leads to a three-dimensional structure which is further stabilized by weak π–π inter­actions of adjacent phen ligands with centroid–centroid separations of 4.2932 (1) Å. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011514/ /pubmed/21589312 http://dx.doi.org/10.1107/S1600536810048142 Text en © Cai et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cai, Yi-Ni
Chen, Jing
Feng, Yun-Long
Aqua­[2-(3-carb­oxy-5-carboxyl­atophen­oxy)acetato-κO (1)]bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate
title Aqua­[2-(3-carb­oxy-5-carboxyl­atophen­oxy)acetato-κO (1)]bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate
title_full Aqua­[2-(3-carb­oxy-5-carboxyl­atophen­oxy)acetato-κO (1)]bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate
title_fullStr Aqua­[2-(3-carb­oxy-5-carboxyl­atophen­oxy)acetato-κO (1)]bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate
title_full_unstemmed Aqua­[2-(3-carb­oxy-5-carboxyl­atophen­oxy)acetato-κO (1)]bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate
title_short Aqua­[2-(3-carb­oxy-5-carboxyl­atophen­oxy)acetato-κO (1)]bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) dihydrate
title_sort aqua­[2-(3-carb­oxy-5-carboxyl­atophen­oxy)acetato-κo (1)]bis­(1,10-phenanthroline-κ(2) n,n′)manganese(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011514/
https://www.ncbi.nlm.nih.gov/pubmed/21589312
http://dx.doi.org/10.1107/S1600536810048142
work_keys_str_mv AT caiyini aqua23carboxy5carboxylatophenoxyacetatoko1bis110phenanthrolinek2nnmanganeseiidihydrate
AT chenjing aqua23carboxy5carboxylatophenoxyacetatoko1bis110phenanthrolinek2nnmanganeseiidihydrate
AT fengyunlong aqua23carboxy5carboxylatophenoxyacetatoko1bis110phenanthrolinek2nnmanganeseiidihydrate