Diaqua­bis­(3-nitro­benzoato-κO (1))bis­[1H-5-(3-pyrid­yl)-3-(4-pyrid­yl)-1H-1,2,4-triazole-κN (5)]cobalt(II) dihydrate

In the centrosymmetric title compound, [Co(C(7)H(4)NO(4))(2)(C(12)H(9)N(5))(2)(H(2)O)(2)]·2H(2)O, the Co(II) atom, located on an inversion center, is coordinated by two N atoms [Co—N = 2.155 (3) Å] and four O atoms [Co—O = 2.099 (2)–2.117 (3) Å] in a distorted octa­hedral geometry. Inter­molecular N...

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Detalles Bibliográficos
Autores principales: Zhang, Yun-Liang, Liu, Ti-Lou, Sun, Shuang-Jiao, Li, Jie-Hong, Wu, Shi-Qing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011517/
https://www.ncbi.nlm.nih.gov/pubmed/21589272
http://dx.doi.org/10.1107/S1600536810046374
Descripción
Sumario:In the centrosymmetric title compound, [Co(C(7)H(4)NO(4))(2)(C(12)H(9)N(5))(2)(H(2)O)(2)]·2H(2)O, the Co(II) atom, located on an inversion center, is coordinated by two N atoms [Co—N = 2.155 (3) Å] and four O atoms [Co—O = 2.099 (2)–2.117 (3) Å] in a distorted octa­hedral geometry. Inter­molecular N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds link the components into a three-dimensional supramolecular framework.

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