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Bis(μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato)-κ(3) O (1),O (1′):O (3);κ(3) O (3):O (1),O (1′)-bis­[(2-phenyl-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))lead(II)]

In the title compound, [Pb(2)(C(9)H(4)O(6))(2)(C(19)H(12)N(4))(2)], the Pb(II) atom is five-coordinated by two N atoms from a chelating 2-phenyl-1H-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene (L) ligand and three O atoms from two Hbtc ligands (H(3)btc is benzene-1,3,5-tricarb­oxy­lic acid), result...

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Detalles Bibliográficos
Autores principales: Chen, Jing, Wang, Xiang-Cheng, Li, Chun-Xiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011518/
https://www.ncbi.nlm.nih.gov/pubmed/21589318
http://dx.doi.org/10.1107/S1600536810045812
Descripción
Sumario:In the title compound, [Pb(2)(C(9)H(4)O(6))(2)(C(19)H(12)N(4))(2)], the Pb(II) atom is five-coordinated by two N atoms from a chelating 2-phenyl-1H-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene (L) ligand and three O atoms from two Hbtc ligands (H(3)btc is benzene-1,3,5-tricarb­oxy­lic acid), resulting in a distorted PbN(2)O(3) coordination. Two Pb(II) atoms are bridged by the Hbtc ligands, forming a discrete centrosymmetric dinuclear complex. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds and π–π inter­actions between the pyridine and imidazole rings, and between the pyridyl rings of the L ligands [centroid–centroid distances = 3.600 (6) and 3.732 (6) Å] lead to a three-dimensional supra­molecular structure.