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Bis(μ-5-carboxybenzene-1,3-dicarboxylato)-κ(3) O (1),O (1′):O (3);κ(3) O (3):O (1),O (1′)-bis[(2-phenyl-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2) N (7),N (8))lead(II)]
In the title compound, [Pb(2)(C(9)H(4)O(6))(2)(C(19)H(12)N(4))(2)], the Pb(II) atom is five-coordinated by two N atoms from a chelating 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene (L) ligand and three O atoms from two Hbtc ligands (H(3)btc is benzene-1,3,5-tricarboxylic acid), result...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011518/ https://www.ncbi.nlm.nih.gov/pubmed/21589318 http://dx.doi.org/10.1107/S1600536810045812 |
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author | Chen, Jing Wang, Xiang-Cheng Li, Chun-Xiang |
author_facet | Chen, Jing Wang, Xiang-Cheng Li, Chun-Xiang |
author_sort | Chen, Jing |
collection | PubMed |
description | In the title compound, [Pb(2)(C(9)H(4)O(6))(2)(C(19)H(12)N(4))(2)], the Pb(II) atom is five-coordinated by two N atoms from a chelating 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene (L) ligand and three O atoms from two Hbtc ligands (H(3)btc is benzene-1,3,5-tricarboxylic acid), resulting in a distorted PbN(2)O(3) coordination. Two Pb(II) atoms are bridged by the Hbtc ligands, forming a discrete centrosymmetric dinuclear complex. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds and π–π interactions between the pyridine and imidazole rings, and between the pyridyl rings of the L ligands [centroid–centroid distances = 3.600 (6) and 3.732 (6) Å] lead to a three-dimensional supramolecular structure. |
format | Text |
id | pubmed-3011518 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30115182010-12-30 Bis(μ-5-carboxybenzene-1,3-dicarboxylato)-κ(3) O (1),O (1′):O (3);κ(3) O (3):O (1),O (1′)-bis[(2-phenyl-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2) N (7),N (8))lead(II)] Chen, Jing Wang, Xiang-Cheng Li, Chun-Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pb(2)(C(9)H(4)O(6))(2)(C(19)H(12)N(4))(2)], the Pb(II) atom is five-coordinated by two N atoms from a chelating 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene (L) ligand and three O atoms from two Hbtc ligands (H(3)btc is benzene-1,3,5-tricarboxylic acid), resulting in a distorted PbN(2)O(3) coordination. Two Pb(II) atoms are bridged by the Hbtc ligands, forming a discrete centrosymmetric dinuclear complex. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds and π–π interactions between the pyridine and imidazole rings, and between the pyridyl rings of the L ligands [centroid–centroid distances = 3.600 (6) and 3.732 (6) Å] lead to a three-dimensional supramolecular structure. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011518/ /pubmed/21589318 http://dx.doi.org/10.1107/S1600536810045812 Text en © Chen et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chen, Jing Wang, Xiang-Cheng Li, Chun-Xiang Bis(μ-5-carboxybenzene-1,3-dicarboxylato)-κ(3) O (1),O (1′):O (3);κ(3) O (3):O (1),O (1′)-bis[(2-phenyl-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2) N (7),N (8))lead(II)] |
title | Bis(μ-5-carboxybenzene-1,3-dicarboxylato)-κ(3)
O
(1),O
(1′):O
(3);κ(3)
O
(3):O
(1),O
(1′)-bis[(2-phenyl-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
N
(7),N
(8))lead(II)] |
title_full | Bis(μ-5-carboxybenzene-1,3-dicarboxylato)-κ(3)
O
(1),O
(1′):O
(3);κ(3)
O
(3):O
(1),O
(1′)-bis[(2-phenyl-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
N
(7),N
(8))lead(II)] |
title_fullStr | Bis(μ-5-carboxybenzene-1,3-dicarboxylato)-κ(3)
O
(1),O
(1′):O
(3);κ(3)
O
(3):O
(1),O
(1′)-bis[(2-phenyl-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
N
(7),N
(8))lead(II)] |
title_full_unstemmed | Bis(μ-5-carboxybenzene-1,3-dicarboxylato)-κ(3)
O
(1),O
(1′):O
(3);κ(3)
O
(3):O
(1),O
(1′)-bis[(2-phenyl-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
N
(7),N
(8))lead(II)] |
title_short | Bis(μ-5-carboxybenzene-1,3-dicarboxylato)-κ(3)
O
(1),O
(1′):O
(3);κ(3)
O
(3):O
(1),O
(1′)-bis[(2-phenyl-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
N
(7),N
(8))lead(II)] |
title_sort | bis(μ-5-carboxybenzene-1,3-dicarboxylato)-κ(3)
o
(1),o
(1′):o
(3);κ(3)
o
(3):o
(1),o
(1′)-bis[(2-phenyl-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
n
(7),n
(8))lead(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011518/ https://www.ncbi.nlm.nih.gov/pubmed/21589318 http://dx.doi.org/10.1107/S1600536810045812 |
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