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Bis(μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato)-κ(3) O (1),O (1′):O (3);κ(3) O (3):O (1),O (1′)-bis­[(2-phenyl-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))lead(II)]

In the title compound, [Pb(2)(C(9)H(4)O(6))(2)(C(19)H(12)N(4))(2)], the Pb(II) atom is five-coordinated by two N atoms from a chelating 2-phenyl-1H-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene (L) ligand and three O atoms from two Hbtc ligands (H(3)btc is benzene-1,3,5-tricarb­oxy­lic acid), result...

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Detalles Bibliográficos
Autores principales: Chen, Jing, Wang, Xiang-Cheng, Li, Chun-Xiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011518/
https://www.ncbi.nlm.nih.gov/pubmed/21589318
http://dx.doi.org/10.1107/S1600536810045812
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author Chen, Jing
Wang, Xiang-Cheng
Li, Chun-Xiang
author_facet Chen, Jing
Wang, Xiang-Cheng
Li, Chun-Xiang
author_sort Chen, Jing
collection PubMed
description In the title compound, [Pb(2)(C(9)H(4)O(6))(2)(C(19)H(12)N(4))(2)], the Pb(II) atom is five-coordinated by two N atoms from a chelating 2-phenyl-1H-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene (L) ligand and three O atoms from two Hbtc ligands (H(3)btc is benzene-1,3,5-tricarb­oxy­lic acid), resulting in a distorted PbN(2)O(3) coordination. Two Pb(II) atoms are bridged by the Hbtc ligands, forming a discrete centrosymmetric dinuclear complex. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds and π–π inter­actions between the pyridine and imidazole rings, and between the pyridyl rings of the L ligands [centroid–centroid distances = 3.600 (6) and 3.732 (6) Å] lead to a three-dimensional supra­molecular structure.
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spelling pubmed-30115182010-12-30 Bis(μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato)-κ(3) O (1),O (1′):O (3);κ(3) O (3):O (1),O (1′)-bis­[(2-phenyl-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))lead(II)] Chen, Jing Wang, Xiang-Cheng Li, Chun-Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pb(2)(C(9)H(4)O(6))(2)(C(19)H(12)N(4))(2)], the Pb(II) atom is five-coordinated by two N atoms from a chelating 2-phenyl-1H-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene (L) ligand and three O atoms from two Hbtc ligands (H(3)btc is benzene-1,3,5-tricarb­oxy­lic acid), resulting in a distorted PbN(2)O(3) coordination. Two Pb(II) atoms are bridged by the Hbtc ligands, forming a discrete centrosymmetric dinuclear complex. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds and π–π inter­actions between the pyridine and imidazole rings, and between the pyridyl rings of the L ligands [centroid–centroid distances = 3.600 (6) and 3.732 (6) Å] lead to a three-dimensional supra­molecular structure. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011518/ /pubmed/21589318 http://dx.doi.org/10.1107/S1600536810045812 Text en © Chen et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Jing
Wang, Xiang-Cheng
Li, Chun-Xiang
Bis(μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato)-κ(3) O (1),O (1′):O (3);κ(3) O (3):O (1),O (1′)-bis­[(2-phenyl-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))lead(II)]
title Bis(μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato)-κ(3) O (1),O (1′):O (3);κ(3) O (3):O (1),O (1′)-bis­[(2-phenyl-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))lead(II)]
title_full Bis(μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato)-κ(3) O (1),O (1′):O (3);κ(3) O (3):O (1),O (1′)-bis­[(2-phenyl-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))lead(II)]
title_fullStr Bis(μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato)-κ(3) O (1),O (1′):O (3);κ(3) O (3):O (1),O (1′)-bis­[(2-phenyl-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))lead(II)]
title_full_unstemmed Bis(μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato)-κ(3) O (1),O (1′):O (3);κ(3) O (3):O (1),O (1′)-bis­[(2-phenyl-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))lead(II)]
title_short Bis(μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato)-κ(3) O (1),O (1′):O (3);κ(3) O (3):O (1),O (1′)-bis­[(2-phenyl-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))lead(II)]
title_sort bis(μ-5-carb­oxy­benzene-1,3-dicarboxyl­ato)-κ(3) o (1),o (1′):o (3);κ(3) o (3):o (1),o (1′)-bis­[(2-phenyl-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) n (7),n (8))lead(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011518/
https://www.ncbi.nlm.nih.gov/pubmed/21589318
http://dx.doi.org/10.1107/S1600536810045812
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