N-[(E)-1,3-Benzodioxol-5-yl­methyl­idene]-4-methyl­aniline

The two symmetry-independent mol­ecules in the asymmetric unit of the title compound, C(15)H(13)NO(2), differ in conformation, with the virtually planar 4-methyl­aniline (r.m.s. deviations of 0.0511 and 0.0082 Å) and piperonal groups (r.m.s. deviations of 0.0241 and 0.0486 Å) forming dihedral angles...

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Detalles Bibliográficos
Autores principales: Tahir, M. Nawaz, Shad, Hazoor Ahmad, Khan, Muhammad Naeem, Tariq, Riaz H.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011519/
https://www.ncbi.nlm.nih.gov/pubmed/21589572
http://dx.doi.org/10.1107/S1600536810048038
Descripción
Sumario:The two symmetry-independent mol­ecules in the asymmetric unit of the title compound, C(15)H(13)NO(2), differ in conformation, with the virtually planar 4-methyl­aniline (r.m.s. deviations of 0.0511 and 0.0082 Å) and piperonal groups (r.m.s. deviations of 0.0241 and 0.0486 Å) forming dihedral angles of 19.40 (5) and 42.90 (6)°. In the crystal, mol­ecules are linked by C—H⋯O and C—H⋯π inter­actions. The H atoms of the two methyl groups are disordered over two sets of sites of equal occupancy.

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