N-[(E)-1,3-Benzodioxol-5-yl­methyl­idene]-4-methyl­aniline

The two symmetry-independent mol­ecules in the asymmetric unit of the title compound, C(15)H(13)NO(2), differ in conformation, with the virtually planar 4-methyl­aniline (r.m.s. deviations of 0.0511 and 0.0082 Å) and piperonal groups (r.m.s. deviations of 0.0241 and 0.0486 Å) forming dihedral angles...

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Detalles Bibliográficos
Autores principales: Tahir, M. Nawaz, Shad, Hazoor Ahmad, Khan, Muhammad Naeem, Tariq, Riaz H.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011519/
https://www.ncbi.nlm.nih.gov/pubmed/21589572
http://dx.doi.org/10.1107/S1600536810048038
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author Tahir, M. Nawaz
Shad, Hazoor Ahmad
Khan, Muhammad Naeem
Tariq, Riaz H.
author_facet Tahir, M. Nawaz
Shad, Hazoor Ahmad
Khan, Muhammad Naeem
Tariq, Riaz H.
author_sort Tahir, M. Nawaz
collection PubMed
description The two symmetry-independent mol­ecules in the asymmetric unit of the title compound, C(15)H(13)NO(2), differ in conformation, with the virtually planar 4-methyl­aniline (r.m.s. deviations of 0.0511 and 0.0082 Å) and piperonal groups (r.m.s. deviations of 0.0241 and 0.0486 Å) forming dihedral angles of 19.40 (5) and 42.90 (6)°. In the crystal, mol­ecules are linked by C—H⋯O and C—H⋯π inter­actions. The H atoms of the two methyl groups are disordered over two sets of sites of equal occupancy.
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spelling pubmed-30115192010-12-30 N-[(E)-1,3-Benzodioxol-5-yl­methyl­idene]-4-methyl­aniline Tahir, M. Nawaz Shad, Hazoor Ahmad Khan, Muhammad Naeem Tariq, Riaz H. Acta Crystallogr Sect E Struct Rep Online Organic Papers The two symmetry-independent mol­ecules in the asymmetric unit of the title compound, C(15)H(13)NO(2), differ in conformation, with the virtually planar 4-methyl­aniline (r.m.s. deviations of 0.0511 and 0.0082 Å) and piperonal groups (r.m.s. deviations of 0.0241 and 0.0486 Å) forming dihedral angles of 19.40 (5) and 42.90 (6)°. In the crystal, mol­ecules are linked by C—H⋯O and C—H⋯π inter­actions. The H atoms of the two methyl groups are disordered over two sets of sites of equal occupancy. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011519/ /pubmed/21589572 http://dx.doi.org/10.1107/S1600536810048038 Text en © Tahir et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tahir, M. Nawaz
Shad, Hazoor Ahmad
Khan, Muhammad Naeem
Tariq, Riaz H.
N-[(E)-1,3-Benzodioxol-5-yl­methyl­idene]-4-methyl­aniline
title N-[(E)-1,3-Benzodioxol-5-yl­methyl­idene]-4-methyl­aniline
title_full N-[(E)-1,3-Benzodioxol-5-yl­methyl­idene]-4-methyl­aniline
title_fullStr N-[(E)-1,3-Benzodioxol-5-yl­methyl­idene]-4-methyl­aniline
title_full_unstemmed N-[(E)-1,3-Benzodioxol-5-yl­methyl­idene]-4-methyl­aniline
title_short N-[(E)-1,3-Benzodioxol-5-yl­methyl­idene]-4-methyl­aniline
title_sort n-[(e)-1,3-benzodioxol-5-yl­methyl­idene]-4-methyl­aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011519/
https://www.ncbi.nlm.nih.gov/pubmed/21589572
http://dx.doi.org/10.1107/S1600536810048038
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