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A 2:1 cocrystal of the cis and trans isomers of bis­[1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato(1−)-κ(2) O,O′]bis­(4-phenyl­pyridine N-oxide-κO)copper(II)

The title compound is a co-crystal of the cis and trans isomers, namely cis-bis­[1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato(1−)-κ(2) O,O′]bis­(4-phenyl­pyridine N-oxide-κO)copper(II)–trans-bis­[1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato(1−)-κ(2) O,O′]bis(4-phenyl­pyridine N-oxide-κO)copper(II) (2/...

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Detalles Bibliográficos
Autores principales: Fernandes, José A., Ramos, Ana I., Braga, Susana S., Almeida Paz, Filipe A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011520/
https://www.ncbi.nlm.nih.gov/pubmed/21589345
http://dx.doi.org/10.1107/S1600536810049196
Descripción
Sumario:The title compound is a co-crystal of the cis and trans isomers, namely cis-bis­[1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato(1−)-κ(2) O,O′]bis­(4-phenyl­pyridine N-oxide-κO)copper(II)–trans-bis­[1,1,1,5,5,5-hexa­fluoro­pentane-2,4-dionato(1−)-κ(2) O,O′]bis(4-phenyl­pyridine N-oxide-κO)copper(II) (2/1), [Cu(C(5)HF(6)O(2))(2)(C(11)H(9)NO)(2)]. In both isomers, the coordination geometry of the Cu(2+) atom is octa­hedral, exhibiting typical Jahn–Teller distortion. The metal atom of the trans isomer is located on an inversion centre. In the cis isomer, the phenyl ring in one 4-phenyl­pyridine N-oxide ligand is disordered over two orientations in a 1:1 ratio. In the crystal, weak inter­molecular C—H⋯F and C—H⋯O contacts establish connections between the cis and trans isomers.