2,4-Dichloro-N-(1,3-thia­zol-2-yl)benzamide

In the mol­ecular structure of the title compound, C(10)H(6)Cl(2)N(2)OS, the dihedral angle between the benzene plane and the plane defined by the amide functionality is 8.6 (1)°, while the thia­zole ring plane is twisted with respect to the amide plane by 68.71 (5)°. In the crystal, pairs of inter­...

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Detalles Bibliográficos
Autores principales: Saeed, Sohail, Rashid, Naghmana, Wong, Wing-Tak
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011524/
https://www.ncbi.nlm.nih.gov/pubmed/21589387
http://dx.doi.org/10.1107/S1600536810044193
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author Saeed, Sohail
Rashid, Naghmana
Wong, Wing-Tak
author_facet Saeed, Sohail
Rashid, Naghmana
Wong, Wing-Tak
author_sort Saeed, Sohail
collection PubMed
description In the mol­ecular structure of the title compound, C(10)H(6)Cl(2)N(2)OS, the dihedral angle between the benzene plane and the plane defined by the amide functionality is 8.6 (1)°, while the thia­zole ring plane is twisted with respect to the amide plane by 68.71 (5)°. In the crystal, pairs of inter­molecular N—H⋯N hydrogen-bond inter­actions connect the mol­ecules into inversion dimers. π–π inter­actions are also observed between neighbouring thia­zole and phen­yl rings [centroid–centroid distance = 3.5905 (13) Å] and a weak C—H⋯π interaction also occurs.
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spelling pubmed-30115242010-12-30 2,4-Dichloro-N-(1,3-thia­zol-2-yl)benzamide Saeed, Sohail Rashid, Naghmana Wong, Wing-Tak Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecular structure of the title compound, C(10)H(6)Cl(2)N(2)OS, the dihedral angle between the benzene plane and the plane defined by the amide functionality is 8.6 (1)°, while the thia­zole ring plane is twisted with respect to the amide plane by 68.71 (5)°. In the crystal, pairs of inter­molecular N—H⋯N hydrogen-bond inter­actions connect the mol­ecules into inversion dimers. π–π inter­actions are also observed between neighbouring thia­zole and phen­yl rings [centroid–centroid distance = 3.5905 (13) Å] and a weak C—H⋯π interaction also occurs. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011524/ /pubmed/21589387 http://dx.doi.org/10.1107/S1600536810044193 Text en © Saeed et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Saeed, Sohail
Rashid, Naghmana
Wong, Wing-Tak
2,4-Dichloro-N-(1,3-thia­zol-2-yl)benzamide
title 2,4-Dichloro-N-(1,3-thia­zol-2-yl)benzamide
title_full 2,4-Dichloro-N-(1,3-thia­zol-2-yl)benzamide
title_fullStr 2,4-Dichloro-N-(1,3-thia­zol-2-yl)benzamide
title_full_unstemmed 2,4-Dichloro-N-(1,3-thia­zol-2-yl)benzamide
title_short 2,4-Dichloro-N-(1,3-thia­zol-2-yl)benzamide
title_sort 2,4-dichloro-n-(1,3-thia­zol-2-yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011524/
https://www.ncbi.nlm.nih.gov/pubmed/21589387
http://dx.doi.org/10.1107/S1600536810044193
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AT rashidnaghmana 24dichloron13thiazol2ylbenzamide
AT wongwingtak 24dichloron13thiazol2ylbenzamide

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