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2,4-Dichloro-N-(1,3-thiazol-2-yl)benzamide
In the molecular structure of the title compound, C(10)H(6)Cl(2)N(2)OS, the dihedral angle between the benzene plane and the plane defined by the amide functionality is 8.6 (1)°, while the thiazole ring plane is twisted with respect to the amide plane by 68.71 (5)°. In the crystal, pairs of inter...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011524/ https://www.ncbi.nlm.nih.gov/pubmed/21589387 http://dx.doi.org/10.1107/S1600536810044193 |
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author | Saeed, Sohail Rashid, Naghmana Wong, Wing-Tak |
author_facet | Saeed, Sohail Rashid, Naghmana Wong, Wing-Tak |
author_sort | Saeed, Sohail |
collection | PubMed |
description | In the molecular structure of the title compound, C(10)H(6)Cl(2)N(2)OS, the dihedral angle between the benzene plane and the plane defined by the amide functionality is 8.6 (1)°, while the thiazole ring plane is twisted with respect to the amide plane by 68.71 (5)°. In the crystal, pairs of intermolecular N—H⋯N hydrogen-bond interactions connect the molecules into inversion dimers. π–π interactions are also observed between neighbouring thiazole and phenyl rings [centroid–centroid distance = 3.5905 (13) Å] and a weak C—H⋯π interaction also occurs. |
format | Text |
id | pubmed-3011524 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30115242010-12-30 2,4-Dichloro-N-(1,3-thiazol-2-yl)benzamide Saeed, Sohail Rashid, Naghmana Wong, Wing-Tak Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecular structure of the title compound, C(10)H(6)Cl(2)N(2)OS, the dihedral angle between the benzene plane and the plane defined by the amide functionality is 8.6 (1)°, while the thiazole ring plane is twisted with respect to the amide plane by 68.71 (5)°. In the crystal, pairs of intermolecular N—H⋯N hydrogen-bond interactions connect the molecules into inversion dimers. π–π interactions are also observed between neighbouring thiazole and phenyl rings [centroid–centroid distance = 3.5905 (13) Å] and a weak C—H⋯π interaction also occurs. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011524/ /pubmed/21589387 http://dx.doi.org/10.1107/S1600536810044193 Text en © Saeed et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Saeed, Sohail Rashid, Naghmana Wong, Wing-Tak 2,4-Dichloro-N-(1,3-thiazol-2-yl)benzamide |
title | 2,4-Dichloro-N-(1,3-thiazol-2-yl)benzamide |
title_full | 2,4-Dichloro-N-(1,3-thiazol-2-yl)benzamide |
title_fullStr | 2,4-Dichloro-N-(1,3-thiazol-2-yl)benzamide |
title_full_unstemmed | 2,4-Dichloro-N-(1,3-thiazol-2-yl)benzamide |
title_short | 2,4-Dichloro-N-(1,3-thiazol-2-yl)benzamide |
title_sort | 2,4-dichloro-n-(1,3-thiazol-2-yl)benzamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011524/ https://www.ncbi.nlm.nih.gov/pubmed/21589387 http://dx.doi.org/10.1107/S1600536810044193 |
work_keys_str_mv | AT saeedsohail 24dichloron13thiazol2ylbenzamide AT rashidnaghmana 24dichloron13thiazol2ylbenzamide AT wongwingtak 24dichloron13thiazol2ylbenzamide |