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1-Benzoyl-3-[4-(3-benzoylthioureido)phenyl]thiourea
The molecule of the title compound, C(22)H(18)N(4)O(2)S(2), lies across a crystallographic inversion centre. The molecule adopts a syn–anti configuration with respect to the positions of the carbonyl groups and terminal phenyl rings relative to the thione S atom across the C—N bond. There are two...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011532/ https://www.ncbi.nlm.nih.gov/pubmed/21589477 http://dx.doi.org/10.1107/S160053681004599X |
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author | Woei Hung, Wong Kassim, Mohammad B. |
author_facet | Woei Hung, Wong Kassim, Mohammad B. |
author_sort | Woei Hung, Wong |
collection | PubMed |
description | The molecule of the title compound, C(22)H(18)N(4)O(2)S(2), lies across a crystallographic inversion centre. The molecule adopts a syn–anti configuration with respect to the positions of the carbonyl groups and terminal phenyl rings relative to the thione S atom across the C—N bond. There are two intramolecular N—H⋯O and C—H⋯S hydrogen bonds within each molecule, resulting in the formation of four six-membered S(6) rings. The central and terminal rings make a dihedral angle of 13.55 (15)°. In the crystal, molecules are linked by intermolecular C—H⋯S hydrogen bonds, forming R (2) (2)(14) rings and resulting in zigzag chains. |
format | Text |
id | pubmed-3011532 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30115322010-12-30 1-Benzoyl-3-[4-(3-benzoylthioureido)phenyl]thiourea Woei Hung, Wong Kassim, Mohammad B. Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(22)H(18)N(4)O(2)S(2), lies across a crystallographic inversion centre. The molecule adopts a syn–anti configuration with respect to the positions of the carbonyl groups and terminal phenyl rings relative to the thione S atom across the C—N bond. There are two intramolecular N—H⋯O and C—H⋯S hydrogen bonds within each molecule, resulting in the formation of four six-membered S(6) rings. The central and terminal rings make a dihedral angle of 13.55 (15)°. In the crystal, molecules are linked by intermolecular C—H⋯S hydrogen bonds, forming R (2) (2)(14) rings and resulting in zigzag chains. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011532/ /pubmed/21589477 http://dx.doi.org/10.1107/S160053681004599X Text en © Woei Hung and Kassim 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Woei Hung, Wong Kassim, Mohammad B. 1-Benzoyl-3-[4-(3-benzoylthioureido)phenyl]thiourea |
title | 1-Benzoyl-3-[4-(3-benzoylthioureido)phenyl]thiourea |
title_full | 1-Benzoyl-3-[4-(3-benzoylthioureido)phenyl]thiourea |
title_fullStr | 1-Benzoyl-3-[4-(3-benzoylthioureido)phenyl]thiourea |
title_full_unstemmed | 1-Benzoyl-3-[4-(3-benzoylthioureido)phenyl]thiourea |
title_short | 1-Benzoyl-3-[4-(3-benzoylthioureido)phenyl]thiourea |
title_sort | 1-benzoyl-3-[4-(3-benzoylthioureido)phenyl]thiourea |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011532/ https://www.ncbi.nlm.nih.gov/pubmed/21589477 http://dx.doi.org/10.1107/S160053681004599X |
work_keys_str_mv | AT woeihungwong 1benzoyl343benzoylthioureidophenylthiourea AT kassimmohammadb 1benzoyl343benzoylthioureidophenylthiourea |