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1-Benzoyl-3-[4-(3-benzoyl­thio­ureido)phen­yl]thio­urea

The mol­ecule of the title compound, C(22)H(18)N(4)O(2)S(2), lies across a crystallographic inversion centre. The mol­ecule adopts a syn–anti configuration with respect to the positions of the carbonyl groups and terminal phenyl rings relative to the thione S atom across the C—N bond. There are two...

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Detalles Bibliográficos
Autores principales: Woei Hung, Wong, Kassim, Mohammad B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011532/
https://www.ncbi.nlm.nih.gov/pubmed/21589477
http://dx.doi.org/10.1107/S160053681004599X
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author Woei Hung, Wong
Kassim, Mohammad B.
author_facet Woei Hung, Wong
Kassim, Mohammad B.
author_sort Woei Hung, Wong
collection PubMed
description The mol­ecule of the title compound, C(22)H(18)N(4)O(2)S(2), lies across a crystallographic inversion centre. The mol­ecule adopts a syn–anti configuration with respect to the positions of the carbonyl groups and terminal phenyl rings relative to the thione S atom across the C—N bond. There are two intra­molecular N—H⋯O and C—H⋯S hydrogen bonds within each molecule, resulting in the formation of four six-membered S(6) rings. The central and terminal rings make a dihedral angle of 13.55 (15)°. In the crystal, mol­ecules are linked by inter­molecular C—H⋯S hydrogen bonds, forming R (2) (2)(14) rings and resulting in zigzag chains.
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spelling pubmed-30115322010-12-30 1-Benzoyl-3-[4-(3-benzoyl­thio­ureido)phen­yl]thio­urea Woei Hung, Wong Kassim, Mohammad B. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(22)H(18)N(4)O(2)S(2), lies across a crystallographic inversion centre. The mol­ecule adopts a syn–anti configuration with respect to the positions of the carbonyl groups and terminal phenyl rings relative to the thione S atom across the C—N bond. There are two intra­molecular N—H⋯O and C—H⋯S hydrogen bonds within each molecule, resulting in the formation of four six-membered S(6) rings. The central and terminal rings make a dihedral angle of 13.55 (15)°. In the crystal, mol­ecules are linked by inter­molecular C—H⋯S hydrogen bonds, forming R (2) (2)(14) rings and resulting in zigzag chains. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011532/ /pubmed/21589477 http://dx.doi.org/10.1107/S160053681004599X Text en © Woei Hung and Kassim 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Woei Hung, Wong
Kassim, Mohammad B.
1-Benzoyl-3-[4-(3-benzoyl­thio­ureido)phen­yl]thio­urea
title 1-Benzoyl-3-[4-(3-benzoyl­thio­ureido)phen­yl]thio­urea
title_full 1-Benzoyl-3-[4-(3-benzoyl­thio­ureido)phen­yl]thio­urea
title_fullStr 1-Benzoyl-3-[4-(3-benzoyl­thio­ureido)phen­yl]thio­urea
title_full_unstemmed 1-Benzoyl-3-[4-(3-benzoyl­thio­ureido)phen­yl]thio­urea
title_short 1-Benzoyl-3-[4-(3-benzoyl­thio­ureido)phen­yl]thio­urea
title_sort 1-benzoyl-3-[4-(3-benzoyl­thio­ureido)phen­yl]thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011532/
https://www.ncbi.nlm.nih.gov/pubmed/21589477
http://dx.doi.org/10.1107/S160053681004599X
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