Poly[[diaqua­(μ(2)-5,5-dioxodibenzo[b,d]thio­phene-3,7-dicarboxyl­ato)(μ(2)-ethyl­ene glycol)manganese(II)] dimethyl­acetamide solvate]

In the title complex, {[Mn(C(14)H(6)O(6)S)(C(2)H(6)O(2))(H(2)O)(2)]·C(4)H(9)NO}(n), the Mn(II) ion is six-coordinated in a trans-octa­hedral geometry by two carboxyl­ate O atoms from two 5,5-dioxodibenzo[b,d]thio­phene-3,7-dicarboxyl­ate (L) ligands in a monodentate mode, two O atoms from two ethyl­...

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Detalles Bibliográficos
Autores principales: Yi, Xiu-Chun, Yan, Li, Gao, En-Qing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011537/
https://www.ncbi.nlm.nih.gov/pubmed/21589246
http://dx.doi.org/10.1107/S1600536810045411
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author Yi, Xiu-Chun
Yan, Li
Gao, En-Qing
author_facet Yi, Xiu-Chun
Yan, Li
Gao, En-Qing
author_sort Yi, Xiu-Chun
collection PubMed
description In the title complex, {[Mn(C(14)H(6)O(6)S)(C(2)H(6)O(2))(H(2)O)(2)]·C(4)H(9)NO}(n), the Mn(II) ion is six-coordinated in a trans-octa­hedral geometry by two carboxyl­ate O atoms from two 5,5-dioxodibenzo[b,d]thio­phene-3,7-dicarboxyl­ate (L) ligands in a monodentate mode, two O atoms from two ethyl­ene glycol (EG) mol­ecules and two aqua O atoms. The metal ions are linked by the EG and L ligands, forming two-dimensional coordination networks, which are associated into the three-dimensional structure through O—H⋯O hydrogen bonds.
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spelling pubmed-30115372010-12-30 Poly[[diaqua­(μ(2)-5,5-dioxodibenzo[b,d]thio­phene-3,7-dicarboxyl­ato)(μ(2)-ethyl­ene glycol)manganese(II)] dimethyl­acetamide solvate] Yi, Xiu-Chun Yan, Li Gao, En-Qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Mn(C(14)H(6)O(6)S)(C(2)H(6)O(2))(H(2)O)(2)]·C(4)H(9)NO}(n), the Mn(II) ion is six-coordinated in a trans-octa­hedral geometry by two carboxyl­ate O atoms from two 5,5-dioxodibenzo[b,d]thio­phene-3,7-dicarboxyl­ate (L) ligands in a monodentate mode, two O atoms from two ethyl­ene glycol (EG) mol­ecules and two aqua O atoms. The metal ions are linked by the EG and L ligands, forming two-dimensional coordination networks, which are associated into the three-dimensional structure through O—H⋯O hydrogen bonds. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011537/ /pubmed/21589246 http://dx.doi.org/10.1107/S1600536810045411 Text en © Yi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yi, Xiu-Chun
Yan, Li
Gao, En-Qing
Poly[[diaqua­(μ(2)-5,5-dioxodibenzo[b,d]thio­phene-3,7-dicarboxyl­ato)(μ(2)-ethyl­ene glycol)manganese(II)] dimethyl­acetamide solvate]
title Poly[[diaqua­(μ(2)-5,5-dioxodibenzo[b,d]thio­phene-3,7-dicarboxyl­ato)(μ(2)-ethyl­ene glycol)manganese(II)] dimethyl­acetamide solvate]
title_full Poly[[diaqua­(μ(2)-5,5-dioxodibenzo[b,d]thio­phene-3,7-dicarboxyl­ato)(μ(2)-ethyl­ene glycol)manganese(II)] dimethyl­acetamide solvate]
title_fullStr Poly[[diaqua­(μ(2)-5,5-dioxodibenzo[b,d]thio­phene-3,7-dicarboxyl­ato)(μ(2)-ethyl­ene glycol)manganese(II)] dimethyl­acetamide solvate]
title_full_unstemmed Poly[[diaqua­(μ(2)-5,5-dioxodibenzo[b,d]thio­phene-3,7-dicarboxyl­ato)(μ(2)-ethyl­ene glycol)manganese(II)] dimethyl­acetamide solvate]
title_short Poly[[diaqua­(μ(2)-5,5-dioxodibenzo[b,d]thio­phene-3,7-dicarboxyl­ato)(μ(2)-ethyl­ene glycol)manganese(II)] dimethyl­acetamide solvate]
title_sort poly[[diaqua­(μ(2)-5,5-dioxodibenzo[b,d]thio­phene-3,7-dicarboxyl­ato)(μ(2)-ethyl­ene glycol)manganese(ii)] dimethyl­acetamide solvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011537/
https://www.ncbi.nlm.nih.gov/pubmed/21589246
http://dx.doi.org/10.1107/S1600536810045411
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AT yanli polydiaquam255dioxodibenzobdthiophene37dicarboxylatom2ethyleneglycolmanganeseiidimethylacetamidesolvate
AT gaoenqing polydiaquam255dioxodibenzobdthiophene37dicarboxylatom2ethyleneglycolmanganeseiidimethylacetamidesolvate

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